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COMEDK2024ChemistryCarboxylic Acid DerivativesActual

Among the following compounds, the most acidic is :

Options

  1. A4-methoxybenzoic acid
  2. B4-nitrobenzoic acid
  3. CBenzoic acid
  4. D3, 4-dinitrobenzoic acid

Correct answer

D. 3, 4-dinitrobenzoic acid

Step-by-step solution

The acidity of benzoic acid derivatives is determined by the electronic effects of the substituents present on the benzene ring. The nitro group ( -NO₂ ) is a strong electron-withdrawing group (EWG) due to both its negative inductive effect ( -I ) and negative resonance effect ( -M ). The methoxy group ( -OCH₃ ) is an electron-donating group (EDG) due to its positive resonance effect ( +M ), which outweighs its negative inductive effect ( -I ) at the para position. Comparing the given compounds: 1. 4-methoxybenzoic

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