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COMEDK20269 May 2026Evening ShiftChemistryCoordination CompoundsActual

Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry

Options

  1. A[ Co(NH ₃)₅ Cl ] Cl ₂
  2. B[ Ni(CO) ₄]
  3. C[ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻
  4. D[ CO(NH ₃)( Cl )( en )₂]²⁺

Correct answer

C. [ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻

Step-by-step solution

In option (A), the complex is [ Co(NH ₃)₅ Cl ] Cl ₂ . The central metal ion is Co ³⁺ , which has a 3d^6 configuration. Since NH ₃ acts as a strong field ligand for Co ³⁺ , it causes pairing of electrons, resulting in a low spin, diamagnetic, and octahedral complex. In option (B), the complex is [ Ni(CO) ₄] . The central metal is Ni in the 0 oxidation state, with a 3d¹⁰ configuration. It forms an sp^3 hybridized, tetrahedral, and diamagnetic complex. In option (C), the complex is [ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻ . The ce

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