COMEDK20269 May 2026Evening ShiftChemistryCoordination CompoundsActual
Identify the complex which exhibits all 3 characteristics; paramagnetic; high spin configuration; octahedral geometry
Options
- A[ Co(NH ₃)₅ Cl ] Cl ₂
- B[ Ni(CO) ₄]
- C[ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻
- D[ CO(NH ₃)( Cl )( en )₂]²⁺
Correct answer
C. [ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻
Step-by-step solution
In option (A), the complex is [ Co(NH ₃)₅ Cl ] Cl ₂ . The central metal ion is Co ³⁺ , which has a 3d^6 configuration. Since NH ₃ acts as a strong field ligand for Co ³⁺ , it causes pairing of electrons, resulting in a low spin, diamagnetic, and octahedral complex. In option (B), the complex is [ Ni(CO) ₄] . The central metal is Ni in the 0 oxidation state, with a 3d¹⁰ configuration. It forms an sp^3 hybridized, tetrahedral, and diamagnetic complex. In option (C), the complex is [ Ni(H ₂ O )₂( C ₂ O ₄)₂]²⁻ . The ce