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COMEDK20269 May 2026Morning ShiftChemistryd and f Block ElementsActual

Which one of the following species will impart colour to an aqueous solution?

Options

  1. ACr ³⁺
  2. BCu ^+
  3. CZn ²⁺
  4. DTi ⁴⁺

Correct answer

A. Cr ³⁺

Step-by-step solution

The colour of transition metal ions in aqueous solution is due to d-d transitions, which require the presence of unpaired d-electrons (partially filled d-subshell). The electronic configurations of the given ions are: Cr ³⁺ (Z = 24): [ Ar ] 3d^3 (3 unpaired electrons) Cu ^+ (Z = 29): [ Ar ] 3d¹⁰ (0 unpaired electrons) Zn ²⁺ (Z = 30): [ Ar ] 3d¹⁰ (0 unpaired electrons) Ti ⁴⁺ (Z = 22): [ Ar ] 3d^0 (0 unpaired electrons) Since Cr ³⁺ has a partially filled d-subshell, it will undergo d-d transitions and impart colour t

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