COMEDK20269 May 2026Morning ShiftChemistryd and f Block ElementsActual
The basic character of transition metal monoxides follows the order:
Options
- ATiO > VO > CrO > FeO
- BVO > CrO > TiO > FeO
- CCrO > TiO > FeO > VO
- DFeO > CrO > VO > TiO
Correct answer
A. TiO > VO > CrO > FeO
Step-by-step solution
For transition metal oxides in the same oxidation state, the basic character decreases as we move from left to right across a period. This occurs because the effective nuclear charge increases and the ionic radius of the metal ion decreases ( Ti²⁺ > V²⁺ > Cr²⁺ > Fe²⁺ ). The decrease in size increases the polarizing power of the cation, leading to an increase in the covalent character of the metal-oxygen bond and a corresponding decrease in the basic character. The atomic numbers of the given metals are Ti ( 22 ), V