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COMEDK20269 May 2026Morning ShiftChemistryd and f Block ElementsActual

The basic character of transition metal monoxides follows the order:

Options

  1. ATiO > VO > CrO > FeO
  2. BVO > CrO > TiO > FeO
  3. CCrO > TiO > FeO > VO
  4. DFeO > CrO > VO > TiO

Correct answer

A. TiO > VO > CrO > FeO

Step-by-step solution

For transition metal oxides in the same oxidation state, the basic character decreases as we move from left to right across a period. This occurs because the effective nuclear charge increases and the ionic radius of the metal ion decreases ( Ti²⁺ > V²⁺ > Cr²⁺ > Fe²⁺ ). The decrease in size increases the polarizing power of the cation, leading to an increase in the covalent character of the metal-oxygen bond and a corresponding decrease in the basic character. The atomic numbers of the given metals are Ti ( 22 ), V

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