Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK20269 May 2026Evening ShiftChemistryElectrochemistryActual

Which of the following is always true about a spontaneous cell reaction in a galvanic cell?

Options

  1. AE^o_ cell = 0; G^o < 0; Q_C = K_C
  2. BE^o_ cell 0; Q_C < K_C
  3. CE^o_ cell > 0; G^o K_C
  4. DE^o_ cell > 0; G^o < 0; Q_C < K_C

Correct answer

D. E^o_ cell > 0; G^o < 0; Q_C < K_C

Step-by-step solution

For a spontaneous cell reaction, the change in Gibbs free energy must be negative, i.e., G The relationship between G , the standard Gibbs free energy change G^o , and the reaction quotient Q_C is given by: G = G^o + RT Q_C At equilibrium, G = 0 and Q_C = K_C , so: G^o = -RT K_C Substituting this back into the first equation, we get: G = -RT K_C + RT Q_C = RT ( Q_C K_C ) For the reaction to be spontaneous ( G RT ( Q_C K_C ) In a standard galvanic cell, the standard cell potential is positive, E^o_ cell > 0 . Since

Practice Electrochemistry on Quantrex Academy →

More from Electrochemistry

The G ^o for the reaction, Cd ²⁺(aq) + Zn (s) Zn ²⁺(aq) + Cd (s) is: [E^o_ Cd ²⁺/ Cd = -0.403, E^o_ Zn ²⁺/ Zn = -0.763 V ] 2026Resistance of 0.2 M solution of an electrolyte is 50 . The conductivity of the solution is 1.3 Sm ⁻¹ . If the resistance of 0.4 M solution of the same electrolyte is 260 , its mola 2026Using the data given below, the strongest reducing agent is: E^o_ Cr ₂ O ₇²⁻/ Cr ³⁺ = 1.33 V E^o_ MnO ₄^-/ Mn ²⁺ = 1.51 V E^o_ Cl ₂/ Cl ^- = 1.36 V E^o_ Cr ³⁺/ Cr = -0.74 V 2026The quantity of Ca that can be produced from molten CaCl₂ , with the same quantity of electricity (in coulombs) required to produce 4.8 g of Mg from molten MgCl₂ is: [Atomic mass o 20263.482 10⁻¹ g of Fe gets deposited when an aqueous solution of Ferric sulphate is electrolysed for 20 minutes using a current of "x" amperes. Find "x". (Atomic mass of Fe = 56amu). 2026Consider a Galvanic cell in which the following reactions occurs: Fe ²⁺(aq) + Ag ^+(aq) Fe ³⁺(aq) + Ag (s) . What is the standard potential of the cell? Given: E^0_ ( Ag ^+/ Ag ) = 2026What will be the change in the electrode potential of chromium electrode dipping into chromic sulphate solution, when the electrolyte is diluted 10 times at 25^ C? [ E^0 ( Cr ³⁺/ C 2026Identify the correct mathematical expression which represents the variation in molar conductivity of a weak acid having concentration C and ionisation constant K_a ( _m^ = molar co 2026 Full Electrochemistry list All COMEDK PYQs