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COMEDK202510 May 2025Evening ShiftChemistryGeneral Organic ChemistryActual

Two statements, one Assertion and the other Reason are given. Choose the correct option. Assertion: Heterocyclic compounds like Pyridine and Thiophene are non-aromatic compounds. Reason: According to Huckel rule for a given compound to exhibit aromaticity, the molecule must be planar, cyclic system having delocalised (4 n+2) electrons.

Options

  1. ABoth Assertion and Reason are correct.
  2. BReason is correct but Assertion is incorrect.
  3. CAssertion is correct but Reason is incorrect.
  4. DBoth Assertion and Reason are incorrect.

Correct answer

B. Reason is correct but Assertion is incorrect.

Step-by-step solution

Assertion is incorrect: Pyridine and Thiophene are well-known aromatic compounds. Pyridine has 6 delocalized electrons (3 double bonds), and Thiophene has 6 delocalized electrons (2 double bonds + lone pair of S). Both satisfy Huckel's rule and are aromatic. Reason is correct: Huckel's rule states that a planar, cyclic, fully conjugated system with (4n+2) electrons is aromatic. Reason is correct but Assertion is incorrect.

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