COMEDK2025ChemistryGeneral Organic ChemistryActual
Which of the following is the most stable free radical?
Options
- ACH ₂= C H
- BC H ₃
- C( CH ₃ )₃ C
- D( C ₆ H ₅ )₂ C H
Correct answer
D. ( C ₆ H ₅ )₂ C H
Step-by-step solution
The stability of free radicals is determined by factors such as resonance, hyperconjugation, and inductive effects. Option (1) is a vinyl radical, which is highly unstable due to the sp^2 hybridized carbon atom having the unpaired electron in an sp^2 orbital. Option (2) is a methyl radical, which has no alkyl groups to provide stability through hyperconjugation. Option (3) is a tertiary butyl radical, which is stabilized by hyperconjugation from nine -hydrogen atoms. Option (4) is a diphenylmethyl radical, which is