COMEDK2024Evening ShiftChemistryGeneral Organic ChemistryActual
Identify the compound which is non-aromatic in nature.
Options
- AD
- BC
- CA
- DB
Correct answer
C. A
Step-by-step solution
To determine the aromaticity of the given compounds, we apply Huckel's rule, which states that a planar, cyclic, fully conjugated system with (4n+2) electrons is aromatic, while one with 4n electrons is anti-aromatic. If the molecule is not planar or lacks continuous conjugation, it is non-aromatic. Compound [A] is cyclooctatetraene. It has 8 electrons ( 4n system). However, it adopts a non-planar 'tub' shape to minimize angle strain and avoid anti-aromaticity, making it non-aromatic. Compound [B] is the cyclopenta