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COMEDK2024Morning ShiftChemistryGeneral Organic ChemistryActual

From the following compounds, identify the one which is most acidic.

Options

  1. AD
  2. BB
  3. CA
  4. DC

Correct answer

D. C

Step-by-step solution

The acidity of a compound is determined by the stability of its conjugate base. The more stable the conjugate base, the more acidic the compound. Compound [A] is phenol, which forms a phenoxide ion. The negative charge on the oxygen is delocalized into the benzene ring. Compound [B] is dicyclohexylmethanol, an aliphatic alcohol. It lacks resonance stabilization for its conjugate base and is the least acidic. Compound [C] is p-nitrophenol. The nitro group ( -NO₂ ) is a strong electron-withdrawing group (EWG) due to

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