COMEDK2021ChemistryGeneral Organic Chemistry
Arrange stability of the given carbon cation in decreasing order
Options
- A(iii) >( ii )>( i )>( iv )
- B(i) >( ii )>( iii )>( iv )
- C(iii) >( i )>( ii )> (iv)
- D(ii) >( iii )>( i )> (iv)
Correct answer
A. (iii) >( ii )>( i )>( iv )
Step-by-step solution
The stability of carbocations is determined by the electron-donating or electron-withdrawing nature of the substituents attached to the benzene ring. The carbocations are stabilized by resonance from the lone pairs on the substituents at the para position. The substituents are: (i) -OCH₃ , (ii) -OH , (iii) -NH₂ , and (iv) -Cl . The resonance donating ability of these groups depends on the electronegativity of the atom directly attached to the ring. A less electronegative atom donates its lone pair more effectively