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COMEDK2017ChemistryRedox Reactions

When sulphur dioxide is passed in an acidified K ₂ Cr ₂ O ₇ solution, the oxidation state of sulphur is changed from

Options

  1. A0 +4 to 0
  2. B+4 to +2
  3. C+4 to +6
  4. D+6 to +4

Correct answer

C. +4 to +6

Step-by-step solution

3 SO ₂+ K ₂ Cr ₂ O ₇+ H ₂ SO ₄ K ₂ SO ₄+ Cr ₂ ( SO ₄ )₃+ H ₂ O O.N. of S in SO ₂ is aligned x+2(-2) &=0 x &=+4 aligned O.N. of S in K ₂ SO ₄ is aligned 2(1)+x+2(-4) &=0 x &=+6 aligned O.N. changes from +4 to +6 .

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