Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
COMEDK2024ChemistryThermodynamics (C)

At 300 K , one mole of ideal gas in thermal contact with surrounding expands isothermally from 1.0 L to 2.0 L against a constant pressure of 3.0 atm. In this process the change in entropy of surrounding ( S_ surr ) in J/K. (1 ~L ~atm =101.3 ~J )

Options

  1. A6.763
  2. B1.013
  3. C-1.013
  4. D-6.673

Correct answer

C. -1.013

Step-by-step solution

S_ surrounding = q_ surrounding T = -q_ system T = W_ system T (For isothermal process, U=0, q=-W ) aligned & W_ system =-P_ ext (V_f-V_i ) & =-3(2-1)=-3 ~L ~atm & aligned S_ surrounding = & -3 300 ~L ~atm =-0.01 Latm & =-0.01 101.3 ~J =-1.013 ~J aligned aligned

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

Identify the INCORRECT statement 2026The standard enthalpies of formation of CH₄ (g), CO₂ (g) and H₂ O(l) are -74.8 kJ mol ⁻¹ , -393.5 kJ mol ⁻¹ and -285.8 kJ mol ⁻¹ respectively. Then the enthalpy change for the give 2026For an ideal gas undergoing an isothermal change, there is 2026Ozone is formed by the reaction O _ 2(g) + O _ (g) O _ 3(g) , H = -107.2 kJ . Given O=O bond energy is 498.0 kJ mol ⁻¹ , the average bond energy of ozone is: 2026H and S for a reaction are 35.5 kJ mol ⁻¹ and 83.6 J K ⁻¹ respectively. Assuming that H and S do not vary with temperature, the reaction is spontaneous when: 2026The heat of combustion of carbon to CO ₂ is -393.5 kJ mol ⁻¹ . The heat released on the formation of 35.2 g of CO ₂ by combustion of C is: 20265 moles of a gas is allowed to pass through a series of changes as shown in the graph, in a cyclic process. The processes C A , B C and A B respectively are 20251 mole of an ideal gas is allowed to expand isothermally and reversibly from 1 L to 5 L at 300 K. The change in enthalpy (in kJ ) is ( R =8.3 ~J ~K ⁻¹ ~mol ⁻¹ ) 2025 Full Thermodynamics (C) list All COMEDK PYQs