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JEE Advanced 2006
Exam
JEE Advanced
Year
2006
Subject
Chemistry
Chapter
General Principles and Processes of Isolation of Metals

JEE Advanced 2006 · Chemistry · General Principles and Processes of Isolation of Metals

Match the extraction processes listed in column I with metals...

Match the extraction processes listed in column I with metals listed in column II. Match the extraction processes listed in column I with metals listed in column II.

Options

  1. A(A) P,S, (B) R, (C) P,Q, (D) P,S
  2. B(A) Q,S, (B) R, (C) S, (D) S
  3. C(A) P,R, (B) P, R, (C) Q, (D) R
  4. D(A) P,R, (B) P, (C) Q, (D) S

Correct answer

D. (A) P,R, (B) P, (C) Q, (D) S

Step-by-step solution

Column I Column II (A) Self reduction \left[P - Lead R - Copper \begin{array}{c}P \text{ - Lead } \\ R \text{ - Copper }\end{array}\right]\begin{aligned}& \text{ i.e., }A \rightleftarrows P \text{ and }R \\ & \text{ In lead metal }\\ & \qquad\left\{\begin{\text{ array }}{c} 2 \mathrm{PbS}+3 \mathrm{O}}_{2} \longrightarrow 2 \mathrm{PbO}+2 \mathrm{SO}}_{2} \\ 2 \mathrm{PbO}+\mathrm{PbS} \longrightarrow3 \mathrm{ Pb}+\mathrm{SO}_{2} \end{array}\right. \end{aligned}(selfreduction)Incoppermetal(self reduction) In copper metal\begin{aligned}& 2 \mathrm{Cu}}_{2} \mathrm{ S}+3 \mathrm{O}_{2} \longrightarrow 2 \mathrm{Cu}}_{2} \mathrm{O}+2 \mathrm{SO}_{2} \\ & \mathrm{Cu}}_{2} \mathrm{ S}+2 \mathrm{Cu}_{2} \mathrm{O} \longrightarrow6 \mathrm{Cu}+\mathrm{SO}}_{2} \end{aligned}(selfreduction)(B)Carbonreduction(self reduction) (B) Carbon reduction P−lead-lead i.e., B−P In lead metal PbO+C⟶Pb+COPbO+CO⟶Pb+CO2\begin{aligned} & \text{ i.e., } \mathrm{B}-\mathrm{P}\\ & \text{ In lead metal }\\ & \qquad \mathrm{PbO}+\mathrm{C} \longrightarrow \mathrm{Pb}+\mathrm{CO}\\ & \mathrm{PbO}+\mathrm{CO} \longrightarrow \mathrm{Pb}+\mathrm{CO}_{2} \end{aligned}CarbonreductionprocessisusedforthereductionofoxidesofelectropositivemetalslikeFe,Pbetc.Thisreductioniscarriedoutwithcoalorcokeonstronglyheating.(C)Complexformationanddisplacementbymetal.i.e.,Carbon reduction process is used for the reduction of oxides of electropositive metals like \mathrm{Fe}, \mathrm{Pb} etc. This reduction is carried out with coal or coke on strongly heating. (C) Complex formation and displacement by metal. i.e., C-Q(silver)InsilvermetalArgentitemineralofAg(silver) In silver metal Argentite mineral of \mathrm{Ag}\left(\mathrm{Ag}}_{2}\mathrm{ S}\right)istreatedwithis treated with0.7 \% \mathrm{NaCN} solution in presence of air, therefore firstly sodium argento cyanide complex is formed which on heating with zinc metal, therefore by displacement silver is isolated. Ag2S+4NaCN⟶2Na[Ag(CN)2]+Na2S2Na[Ag(CN)2]+Zn⟶Na[Zn(CN)4]+2Ag Soluble ↓\begin{aligned}& \mathrm{Ag}_2 \mathrm{ S}+4 \mathrm{NaCN} \longrightarrow2 \mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_2\right]+ \mathrm{Na}_2 \mathrm{ S}\\ & 2 \mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_2\right]+ \mathrm{Zn} \longrightarrow \mathrm{Na}\left[\mathrm{Zn}(\mathrm{CN})_4\right]+\underset{\text{ Soluble }}{2 \mathrm{Ag}} \downarrow \end{aligned} (D) Decomposition of iodide-(S) Boron \text{ i.e., }(D)-(S) By decomposition of iodide boron metal is isolated.
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