JEE Advanced 2006
- Exam
- JEE Advanced
- Year
- 2006
- Subject
- Chemistry
- Chapter
- General Principles and Processes of Isolation of Metals
JEE Advanced 2006 · Chemistry · General Principles and Processes of Isolation of Metals
Match the extraction processes listed in column I with metals...
Match the extraction processes listed in column I with metals listed in column II.

Options
- A(A) P,S, (B) R, (C) P,Q, (D) P,S
- B(A) Q,S, (B) R, (C) S, (D) S
- C(A) P,R, (B) P, R, (C) Q, (D) R
- D(A) P,R, (B) P, (C) Q, (D) S
Correct answer
D. (A) P,R, (B) P, (C) Q, (D) S
Step-by-step solution
Column I
Column II
(A) Self reduction \left[\right]\begin{aligned}& \text{ i.e., }A \rightleftarrows P \text{ and }R \\
& \text{ In lead metal }\\
& \qquad\left\{\begin{\text{ array }}{c}
2 \mathrm{PbS}+3 \mathrm{O}}_{2} \longrightarrow 2 \mathrm{PbO}+2 \mathrm{SO}}_{2} \\
2 \mathrm{PbO}+\mathrm{PbS} \longrightarrow3 \mathrm{ Pb}+\mathrm{SO}_{2}
\end{array}\right.
\end{aligned}\begin{aligned}& 2 \mathrm{Cu}}_{2} \mathrm{ S}+3 \mathrm{O}_{2} \longrightarrow 2 \mathrm{Cu}}_{2} \mathrm{O}+2 \mathrm{SO}_{2} \\
& \mathrm{Cu}}_{2} \mathrm{ S}+2 \mathrm{Cu}_{2} \mathrm{O} \longrightarrow6 \mathrm{Cu}+\mathrm{SO}}_{2}
\end{aligned} P C-Q\left(\mathrm{Ag}}_{2}\mathrm{ S}\right)0.7 \% \mathrm{NaCN} solution in presence of air, therefore firstly sodium argento cyanide complex is formed which on heating with zinc metal, therefore by displacement silver is isolated.
(D) Decomposition of iodide-(S) Boron
\text{ i.e., }(D)-(S)
By decomposition of iodide boron metal is isolated.