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JEE Advanced 2019Paper 1
Exam
JEE Advanced
Year
2019
Paper
Paper 1
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Advanced 2019 · Paper 1 · Chemistry · Ionic Equilibrium

For the following reaction, the equilibrium constant K _ e at 298K...

For the following reaction, the equilibrium constant Ke{K}_{e} at 298K298K is 1.6×1017.1.6 \times {10}^{17} .
Fe2+(aq)+S2−(aq)⇌FeS(s)F{e}^{2 +}\left(aq\right) + {S}^{2 -}\left(aq\right) ⇌ FeS\left(s\right)
When equal volumes of 0.06MFe2+(aq)0.06MF{e}^{2 +}\left(aq\right) and 0.2MS2−(aq)0.2M{S}^{2 -}\left(aq\right) solutions are mixed, the equilibrium concentration of Fe2+(aq)F{e}^{2 +}\left(aq\right) is found to be Y×10−17M.Y \times {10}^{- 17}M . The value of YY is __________

Correct answer

0

Step-by-step solution

{\text{Fe}}^{\text{2+}} + {\text{S}}^{\text{2-}} ⇌ \text{Fe}{\text{S}}_{( \text{s} )}..........{\text{K}}_{\text{c}} = 1.6 \times {10}^{17}<br/><br />\text{t} = 0::0.03\text{M}\left(0.1\text{M}\right)<br/><br />\text{t} = \text{t;}\left(0.03 - \text{H}\right)\left(0.1\text{H}\right)<br/>Since<br />Since{\text{K}}_{\text{c}} > > 1,<br/><br />n ≃ 0.03<br/><br />∴ [ {\text{S}}^{\text{2-}} ] = 0.1 - 0.031 = 0.07\text{M}<br/><br />{\text{K}}_{\text{c}} = \left[{\text{Fe}}^{2 +}\right]\left[{\text{S}}^{\text{2-}}\right] = \dfrac{1}{1.6 \times {10}^{17}}<br/>[Fe2+]=11.6×0.07×10−17<br />\left[{\text{Fe}}^{2 +}\right] = \dfrac{1}{1.6 \times 0.07} \times {10}^{- 17}
y=11.6×0.07≃8.93\text{y} = \dfrac{1}{1.6 \times 0.07} ≃ 8.93
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