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JEE Advanced 2013Paper 2
Exam
JEE Advanced
Year
2013
Paper
Paper 2
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Advanced 2013 · Paper 2 · Chemistry · Ionic Equilibrium

The K _ sp of Ag _ 2 CrO _ 4 is 1 . 1 × 1 0 ^ - 1 2 at 298K . The...

The Ksp{K}_{sp} of Ag2CrO4{\text{Ag}}_{2}{\text{CrO}}_{4} is 1.1×10−121 . 1 \times 1 {0}^{- 1 2} at 298K298K. The solubility (in molL−1mol{L}^{- 1})ofAg2CrO4of {\text{Ag}}_{2}CrO{}_{4} in a 0.1MAgNO30 . 1M{\text{AgNO}}_{3} solution is

Options

  1. A1.1×10−111 \text{.} 1 × 1 {0}^{- 1 1}
  2. B1.1×10−101 \text{.} 1 × 1 {0}^{- 1 0}
  3. C1.1×10−121 \text{.} 1 × 1 {0}^{- 1 2}
  4. D1.1×10−91 \text{.} 1 × 1 {0}^{- 9}

Correct answer

B. 1.1×10−101 \text{.} 1 × 1 {0}^{- 1 0}

Step-by-step solution

{Ag2CrO4(s)⇌2Ag+(aq)+CrO42−(2S)molar(S)molar\begin{cases}{Ag}_{2}{CrO}_{4}\left(s\right) & ⇌ & 2{Ag}^{+}\left(aq\right) & + & {CrO}_{4}^{2 -} \\ \left(2\text{S}\right)\text{molar} & \left(\text{S}\right)\text{molar}\end{cases}
{AgNO3(aq)⟶Ag+(aq)+NO3−(aq)(0.1)molar(0.1)molar\begin{cases}{AgNO}_{3}\left(aq\right) & ⟶ & {Ag}^{+}\left(aq\right) & + & {NO}_{3}^{-}\left(aq\right) \\ \left(0\text{.}1\right)\text{molar} & \left(0\text{.}1\right)\text{molar}\end{cases}
\left[{Ag}^{+}\right] = \left(2S + 0 . 1\right)molar<br/>[CrO42−]=(S)molar<br />\left[{CrO}_{4}^{2 -}\right] = \left(S\right)\text{molar}
Here, SS is the solubility of Ag2CrO4{Ag}_{2}{CrO}_{4} in aqueous~ AgNO3{AgNO}_{3}.

⇒[Ag+]2[CrO42−]=(2S+0.1)2(S)=1.1×10−12⇒{\left[{Ag}^{+}\right]}^{2 } \left[{CrO}_{4}^{2 -}\right] = {\left(2 \text{S} + 0 \text{.} 1\right)}^{2} \left(\text{S}\right) = 1 \text{.} 1 \times 1 {0}^{- 1 2}
S≪0.1\text{S} ≪ 0 \text{.} 1
⇒(0.1)2(S)=1.1×10−12=10−2×SS=1.1×10−10M⇒\left(0 . 1\right)2\left(S\right) = 1 . 1 \times {10}^{- 12} = {10}^{- 2} \times SS = 1 . 1 \times {10}^{- 10}M

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