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JEE Advanced 2006
Exam
JEE Advanced
Year
2006
Subject
Chemistry
Chapter
s Block Elements

JEE Advanced 2006 · Chemistry · s Block Elements

MgSO_4 on reaction with NH_4 OH and Na_2 HPO_4 forms a white...

MgSO4\mathrm{MgSO}_4 on reaction with NH4OH\mathrm{NH}_4 \mathrm{OH} and Na2HPO4\mathrm{Na}_2 \mathrm{HPO}_4 forms a white crystalline precipitate. What is its formula?MgSO_4 on reaction with NH_4 OH and Na_2 HPO_4 forms a white crystalline precipitate. What is its formula?

Options

  1. AMg(NH4)PO4\mathrm{Mg}\left(\mathrm{NH}_4\right) \mathrm{PO}_4
  2. BMg3(PO4)2\mathrm{Mg}_3\left(\mathrm{PO}_4\right)_2
  3. CMgCl2⋅MgSO4\mathrm{MgCl}_2 \cdot \mathrm{MgSO}_4
  4. DMgSO4\mathrm{MgSO}_4

Correct answer

A. Mg(NH4)PO4\mathrm{Mg}\left(\mathrm{NH}_4\right) \mathrm{PO}_4

Step-by-step solution

\mathrm{MgSO}_4onreactionwithon reaction with\mathrm{Na}_2 \mathrm{HPO}_4(disodiumhydrogenphosphate)inpresenceof(disodium hydrogen phosphate) in presence of\mathrm{NH}_4 \mathrm{OH}togivewhiteprecipitateofmagnesiumammoniumphosphate(Mg(NH4)PO4)to give white precipitate of magnesium ammonium phosphate \left(\mathrm{Mg}\left(\mathrm{NH}_4\right) \mathrm{PO}_4\right). MgSO_4 on reaction with NH_4 OH and Na_2 HPO_4 forms a white crystalline precipitate. What is its formula?
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