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JEE s Block Elements PYQs with Solutions

275 previous year questions from s Block Elements (JEE Main & Advanced Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

275 questionsChemistry2002–2026Answers + solutions

About s Block Elements PYQs

s Block Elements has 275 previous year questions in the Quantrex Academy JEE Main & Advanced Chemistry bank. The 220 questions in this list come from JEE Main (134), NTA Abhyas JEE Main (82) and JEE Advanced (4), spanning 2002 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 2
  • 2023: 38
  • 2022: 20
  • 2021: 23
  • 2020: 93
  • 2019: 14
  • 2018: 2
  • 2017: 3
  • 2016: 3
  • 2015: 3
  • 2014: 2
  • 2013: 2

s Block Elements questions with solutions

1

First and second ionization enthalpies of lithium are 520 kJ mol ^ -1 and 7297 kJ mol ^ -1 respectively. Energy required to convert 3.5 mg lithium (g) into Li^ 2+ (g) [Li(g) arrow

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2

The correct set that contains all kinds (basic, acidic, amphoteric and neutral) of oxides is:

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3

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R : Assertion (A) : BeCl _ 2 and MgCl _ 2 produce characteristic flame Reason

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4

Be ( OH ) _ 2 reacts with Sr ( OH ) _ 2 to yield an ionic salt. Choose the incorrect option related to this reaction from the following

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5

In the given reaction cycle X, Y and Z respectively are

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6

The density of alkali metals is in the order

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7

Alkali metal from the following with least melting point is

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8

Mg ( NO _ 3 ) _ 2 . XH _ 2 O and Ba ( NO _ 3 ) _ 2 . YH _ 2 O , represent formula of the crystalline forms of nitrate salts. Sum of X and Y is.......

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9

Match List-I with List-II: List-I List-II A. K I. Thermonuclear reactions B. KCI II. Fertilizer C. KOH III. Sodium potassium pump D. Li IV. Absorbent of CO _ 2

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10

Number of water molecules in washing soda and soda ash respectively are :

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11

Lime reacts exothermally with water to give ‘ A ’ which has low solubility in water. Aqueous solution of ‘ A ’ is often used for the test of CO _ 2 , a

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12

In the following reaction, the total number of oxygen atoms in X and Y is______ Na _ 2 O + H _ 2 O → 2X Cl _ 2 O _ 7 + H _ 2 O → 2Y

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13

For a good quality cement, the ratio of lime to the total of the oxides of Si, Al and Fe should be as close as to

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14

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R Assertion A : Sodium is about 30 times as abundant as potassium in the oceans.

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15

Given below are two statements : Statement I : Lithium and Magnesium do not form superoxide Statement II : The ionic radius of Li ^ + is larger than ionic radius of Mg ^ 2 + In

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16

What is the purpose of adding gypsum to cement?

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17

Ion having highest hydration enthalpy among the given alkaline earth metal ions is:

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18

The setting time of Cement is increased by adding

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19

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Gypsum is used for making fireproof wall boards. Reason

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20

Match List I with List II (A) Slaked lime (I) NaOH (B) Dead burnt plaster (II) Ca ( OH ) _ 2 (C) Caustic soda (III) Na _ 2 CO _ 3 · 10 H _ 2 O (D) Washing soda (IV) CaSO _ 4

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21

Choose the correct statement(s): A. Beryllium oxide is purely acidic in nature. B. Beryllium carbonate is kept in the atmosphere of CO _ 2 . C. Beryllium sulphate is readily

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22

The element playing significant role in neuromuscular function and interneuronal transmission is :

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23

The number of alkali metal(s), from Li, K, Cs, Rb having ionization enthalpy greater than 400kJ mol ^ - 1 and forming stable super oxide is

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24

Chlorides of which metal are soluble in organic solvents:

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25

Which of the following reaction is correct?

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26

The alkaline earth metal sulphate(s) which are readily soluble in water is/are: (A) BeSO _ 4 (B) MgSO _ 4 (C) CaSO _ 4 (D) SrSO _ 4 (E) BaSO _ 4 Choose the correct answer from the

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27

Lithium aluminium hydride can be prepared from the reaction of

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28

On heating, LiNO _ 3 gives how many compounds among the following? Li _ 2 O, N _ 2 , O _ 2 , LiNO _ 2 , NO _ 2

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29

The magnetic behaviour of Li _ 2 O , Na _ 2 O _ 2 and KO _ 2 , respectively, are

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30

The correct order of hydration enthalpies is (A) K ^ + (B) Rb ^ + (C) Mg ^ 2 + (D) Cs ^ + (E) Ca ^ 2 + Choose the correct answer from the options given below:

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31

Match List I with List II List I List II A. Cobalt catalyst I. ( H _ 2 + Cl _ 2 ) production B. Syngas II. Water gas production C. Nickel catalyst III. Coal gasification D. Brine

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32

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R Assertion A:- The alkali metals and their salts impart characteristic colour

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33

Which one among the following metals is the weakest reducing agent?

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34

Which of the following represents the correct order of metallic character of the given elements?

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35

Match List I with List II List I List II Elements Colour imparted to the flame A K I Brick Red B Ca II Violet C Sr III Apple Green D Ba IV Crimson Red Choose the correct answer

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36

Identify the correct statements about alkali metals. A. The order of standard reduction potential ( M ^ + | M ) for alkali metal ions is Na > Rb > Li . B. CsI is highly soluble in

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37

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R . Assertion A : Beryllium has less negative value of reduction potential

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38

The number of s-electrons present in an ion with 55 protons in its unipositive state is

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39

Match Column I with Column II Column I Column II A Soda ash I CaSO _ 4 B Chlorophyll II Ca (OH) _ 2 C Used in Whitewashing III Na _ 2 CO _ 3 D Dentistry, ornamental work IV Mg ^ 2

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40

Reaction of BeO with ammonia and hydrogen fluoride gives ' A ' which on thermal decomposition gives BeF _ 2 and NH _ 4 F . What is ' A ' ?

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41

Portland cement contains ' X ' to enhance the setting time. What is ' X '?

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42

Lithium nitrate and sodium nitrate, when heated separately, respectively, give

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43

Statement I: An alloy of lithium and magnesium is used to make aircraft plates. Statement II : The magnesium ions are important for cell-membrane integrity. In the light the above

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44

Which of the following statement is incorrect?

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45

An element A of group 1 shows similarity to an element B belonging to group 2 . If A has maximum hydration enthalpy in group 1 then B is

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46

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R . Assertion A : LiF is sparingly soluble in water. Reason R : The ionic radius

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47

Reaction of BeCl _ 2 with LiAlH _ 4 gives : (A) AlCl _ 3 (B) BeH _ 2 (C) LiH (D) LiCl (E) BeAlH _ 4 Choose the correct answer from options given below

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48

The correct order of density is

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49

Choose the correct order of density of the alkali metals

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50

Amongst baking soda, caustic soda and washing soda carbonate anion is present in :

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51

Match List-I with Match List-II List-I (Metal) List-II (Emitted light wavelength (nm) ) (A) Li (I) 670 . 8 (B) Na (II) 589 . 2 (C) Rb (III) 780 . 0 (D) Cs (V) 455 . 5 Choose the

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52

Among the following, basic oxide is

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53

BeO reacts with HF in presence of ammonia to give [A] which on thermal decomposition produces [B] and ammonium fluoride. Oxidation state of Be in [A] is

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54

Addition of H _ 2 SO _ 4 to BaO _ 2 produces

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55

BeCl _ 2 reacts with LiAlH _ 4 to give

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56

s-block element which cannot be qualitatively confirmed by the flame test is

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57

The correct order of melting point is

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58

Which one of the following alkaline earth metal ions has the highest ionic mobility in its aqueous solution?

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59

Which one of the following compounds is used as a chemical in certain type of fire extinguishers

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60

Which of the following statements are correct ? (A) Both LiCl and MgCl _ 2 are soluble in ethanol. (B) The oxides Li _ 2 O and MgO combine with excess of oxygen to give

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61

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Lithium salts are hydrated. Reason (R) : Lithium has

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62

The major component/ingredient of Portland Cement is :

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63

The oxide that gives H _ 2 O _ 2 most readily on treatment with H _ 2 O is :

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64

Choose the correct statement from the following :

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65

The number of water molecules in gypsum, dead burnt plaster and plaster of Paris, respectively are:

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66

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Barium carbonate is insoluble in water and is highly

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67

What are the products formed in sequence when excess of CO _ 2 is passed in slaked lime?

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68

Match List - I with List II : List-I List-II a Li i photoelectric cell b Na ii absorbent of CO _ 2 c K iii coolant in fast breeder nuclear reactor d Cs iv treatment of cancer v

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69

Match List I with List II : List-I Elements List-II Properties (a) Li (i) Poor water solubility of I ^ - salt (b) Na (ii) Most abundant element in cell fluid (c) K (iii)

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70

Given below are two statements: Statement I : None of the alkaline earth metal hydroxides dissolve in alkali. Srtatement II : Solubility of alkaline earth metal hydroxides in

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71

Match List-I with List-II List - I (Elements) List - II (Properties) (a) Ba ( i ) Organic solvent soluble compounds (b) Ca ( ii ) Outer electronic configuration 6 s ^ 2 (c) Li (

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72

Metallic sodium does not react normally with:

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73

A s-block element (M) reacts with oxygen to form an oxide of the formula MO _ 2 . The oxide is pale yellow in colour and paramagnetic. The element ( M ) is:

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74

Match list-I with list-II : (a) Be (i) Treatment of cancer (b) Mg (ii) Extraction of metals (c) Ca (iii) Incendiary bombs and signals (d) Ra (iv) Windows of X-ray tubes (v)

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75

Match List - I with List - II List - I List - II (a) Ca ( OCl ) _ 2 (i) Antacid (b) CaSO _ 4 · (1)/(2) H _ 2 O (ii) Cement (c) CaO (iii) Bleach (d) CaCO _ 3 (iv) Plaster of paris

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76

The set of elements that differ in mutual relationship from those of the other sets is:

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77

One of the by-products formed during the recovery of NH _ 3 from Solvay process is:

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78

The correct order of conductivity of ions in water is:

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79

Given below are two statements: Statement I : Both CaCl _ 2 . 6 H _ 2 O and MgCl _ 2 . 8 H _ 2 O undergo dehydration on heating. Statement II : BeO is amphoteric, whereas the

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80

Find A, B and C in the following reactions: NH _ 3 + A + CO _ 2 → ( NH _ 4 ) _ 2 CO _ 3 ( NH _ 4 ) _ 2 CO _ 3 + H _ 2 O + B → NH _ 4 HCO _ 3 NH _ 4 HCO _ 3 + NaCl → NH _ 4 Cl + C

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81

Among the following, number of metal/s which can be used as electrodes in the photoelectric cell is ___ . (Integer answer) (A) Li (B) Na (C) Rb (D) Cs

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82

Match List - I with List - II. List-I (Salt) List-II (Flame colour wavelength) (a) LiCl (i) 455 . 5nm (b) NaCl (ii) 670 . 8nm (c) RbCl (iii) 780 . 0nm (d) CsCl (iv) 589 . 2nm

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83

Number of amphoteric compounds among the following is (A) BeO (B) BaO (C) Be (OH) _ 2 (D) Sr (OH) _ 2

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84

Which of the following liberates O _ 2 upon hydrolysis?

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85

Match the following compounds (Column-I) with their uses (Column-II) S. No. Column-I S.No. Column-II (I) Ca (OH) _ 2 (A) casts of statues (II) NaCl (B) white wash (III) CaSO _ 4 ·

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86

Among the sulphates of alkaline earth metals, the solubilities of BeSO _ 4 and MgSO _ 4 in water, respectively, are :

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87

An alkaline earth metal ' M ' readily forms water soluble sulphate and water insoluble hydroxide. Its oxide MO is very stable to heat and does not have rock-salt

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88

On combustion of Li, Na and K in excess of air, the major oxides formed, respectively, are:

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89

Among the statement (I – IV), the correct ones are: (I) Be has smaller atomic radius compared to Mg. (II) Be has higher ionization enthalpy than AI. (III) Charge/radius

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90

Two elements A and B have similar chemical properties. They don't form solid hydrogencarbonates, but react with nitrogen to form nitrides. A and B , respectively, are :

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91

The metal mainly used in devising photoelectric cells is :

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92

Among the statements (a) - (d), the correct ones are: ( a ) Lithium has the highest hydration enthalpy among the alkali metals. ( b ) Lithium chloride is insoluble in pyridine. (

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93

The radius of the second Bohr orbit, in terms of the Bohr radius, a _ 0 , in Li ^ 2 + is:

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94

When gypsum is heated to 393K, it forms:

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95

Which of the following does not illustrate the anomalous properties of lithium?

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96

Alkali metals act as

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97

Which one of the following pairs of substances on reaction will not evolve H _ 2 gas?

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98

The carbonate of which of the following cation is insoluble in water?

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99

Washing soda is Na _ 2 CO _ 3 · x H _ 2 O . The value of ' x ' is ______.

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100

In curing cement plasters water is sprinkled from time to time. This helps in

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101

What is the product of the reaction of H _ 2 O _ 2 With C l _ 2 ?

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102

How many of the following nitrates of metal ‘M’ decompose on heating similar to as given below in the scheme? (where; M = Li , Be, Mg, K, Ca, Sr, Na , Rb, Ba ) Metal nitrate Heat

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103

NaOCl is used as a bleaching agent and sterilising agent. It can be synthesised by the action of

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104

How many of the following metals can be detected in the laboratory through flame test i) Be ii) Mg iii) Na iv) K v) Ba

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105

The compound A on heating gives a colourless gas and a residue that is dissolved in water to obtain B. Excess of CO_ 2 is bubbled through aqueous solution of B, C is formed which

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106

Which one of the following cannot be prepared from B _ 2 H _ 6 ?

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107

Which pair of the following chlorides do not impart colour to the flame?

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108

Which of the following represents the& incorrect order of properties?

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109

Match the reactions given in column (I) with process/products in column (II) and select the proper code of choice from the choices given at the end. & (I) & (II) cases (A)

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110

Which of the following statements is incorrect for hydrogen peroxide?

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111

In the reaction: Zn+ NaNO _ 3 +NaOH → Na _ 2 ZnO _ 2 +A+ H _ 2 O The sum of stoichiometric coefficients of Zn and A in the balanced reaction with simplest integer coefficient is

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112

Least stable peroxide among the following:

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113

Potassium ozonide on decomposition gives

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114

Li_ 3 N+ H _ 2 O → A (gas) Li _ 2 CO _ 3 Δ → B (gas) Hybridisation of the central atom in A and B respectively.

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115

NaN O _ 3 Δ → A _ gas + B A + HCl CuC l _ 2 → C _ gas + H _ 2 O Colour of C and A are respectively.

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116

Lithium hydride reacts with aluminium chloride to form a complex. The geometry of the complex and the ligand present in the complex is

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117

Which of the following ions have maximum hydration energy?

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118

Total number of elements which do not form hydrides are Mo, Ca, Fe, Pd, Co, Ru, W, Cr

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119

Peroxide ion is present in:

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120

Hydrogen peroxide oxidises thiosulphate ion to:-

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