JEE Advanced 2026Paper 2
- Exam
- JEE Advanced
- Year
- 2026
- Paper
- Paper 2
- Subject
- Chemistry
- Chapter
- Solutions
JEE Advanced 2026 · Paper 2 · Chemistry · Solutions
Passage: Two volatile liquids A and B form an ideal solution....
Passage: Two volatile liquids A and B form an ideal solution. Consider a molal solution of B in A inside a closed container having a total vapour pressure of mm Hg at K. The vapour pressure of pure A at K is mm Hg. Assume that A and B behave as ideal gases in the vapour phase.
Given:
The gas constant L atm K mol
Molar mass of A is g mol
Molar mass of B is g mol
Density of liquid B at K is g/mL
atm mm Hg
Question: The mole fraction of B in vapour phase which is in equilibrium with this solution is ____.
Given:
The gas constant L atm K mol
Molar mass of A is g mol
Molar mass of B is g mol
Density of liquid B at K is g/mL
atm mm Hg
Question: The mole fraction of B in vapour phase which is in equilibrium with this solution is ____.
Correct answer
0
Step-by-step solution
Molality of B in A is m, which means moles of B are dissolved in kg ( g) of solvent A.
Number of moles of A, mol
Mole fraction of A in the liquid phase,
Mole fraction of B in the liquid phase,
According to Raoult's law, the partial vapour pressure of A is:
mm Hg
Given total vapour pressure, mm Hg
Partial vapour pressure of B, mm Hg
Mole fraction of B in the vapour phase,
Answer:
Number of moles of A, mol
Mole fraction of A in the liquid phase,
Mole fraction of B in the liquid phase,
According to Raoult's law, the partial vapour pressure of A is:
mm Hg
Given total vapour pressure, mm Hg
Partial vapour pressure of B, mm Hg
Mole fraction of B in the vapour phase,
Answer: