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Solutions — JEE Main & Advanced Chemistry PYQs

493 previous year questions from Solutions with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

In a solvent S , a compound B is partially dissociated into C and D as given below: B 2 C + 2 D B , C and D are non-volatile in nature. The molar mass of B is 10 times the molar ma

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2

Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K.

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3

Passage: Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K.

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4

Given below are two statements: Given: Molar mass of C, H, O, Cl are 12, 1, 16 and 35.5 g mol ⁻¹ , respectively. Statement I: In 30 % (w/w) solution of methanol in CCl ₄ (at T K),

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5

Which of the following statements are not correct? A. For water, magnitude of K_b is more than the magnitude of K_f . B. The elevation in boiling point of water when a non-volatile

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6

Given below are two statements : Statement I : H₂ O molecules move from the chamber 1 to chamber 2 . Statement II : The osmotic pressure of a solution prepared by dissolving 50 mg

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7

When 0.25 moles of a non-volatile, non-ionizable solute was dissolved in 1 mole of a solvent the vapor pressure of solution was x % of vapor pressure of pure solvent. What is x % ?

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8

20 g hemoglobin in a 1 L aqueous solution (A) at 300 K is separated from pure water by semi permeable membrane. At equilibrium the height of solution in a tube dipped in a solution

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9

What is the mole fraction of water in 10 % by weight (w/w) of aqueous urea solution? [Given: Molar mass of H, O, C and N are 1 , 16 , 12 and 14 g mol ⁻¹ respectively.]

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10

At 27° C, 0.1 M, 1 L K₄[Fe(CN)₆] aqueous solution and 0.1 M, 1 L FeCl₃ aqueous solution are placed in a container separated by a semi permeable membrane AB. Assume complete dissoci

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11

A non-volatile, non-electrolyte solid solute when dissolved in 40 g of a solvent, the vapour pressure of the solvent decreased from 760 mm Hg to 750 mm Hg. If the same solution boi

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12

Solution A is prepared by dissolving 1 g of a protein (molar mass = 50000 g mol ⁻¹ ) in 0.5 L of water at 300 K. Its osmotic pressure is x bar. Solution B is made by dissolving 2 g

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13

19.5 g of fluoro acetic acid (molar mass = 78 g mol ⁻¹ ) is dissolved in 500 g of water at 298 K. The depression in the freezing point of water was 1° C. What is K_a of fluoro acet

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14

Given below are two statements : Statement (I) : 1,2,3-Trihydroxypropane can be separated from water by simple distillation. Statement (II) : An azeotropic mixture cannot be separa

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15

Consider the following aqueous solutions. I. 2.2 g Glucose in 125 mL of solution. II. 1.9 g Calcium chloride in 250 mL of solution. III. 9.0 g Urea in 500 mL of solution. IV. 20.5

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16

At T ( K ), 2 moles of liquid A and 3 moles of liquid B are mixed. The vapour pressure of ideal solution formed is 320 mm Hg. At this stage, one mole of A and one mole of B are add

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17

At 298 K, the mole percentage of N ₂( ~g ) in air is 80 % . Water is in equilibrium with air at a pressure of 10 atm. What is the mole fraction of N ₂( ~g ) in water at 298 K ? ( K

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18

Two liquids A and B form an ideal solution at temperature T K. At T K, the vapour pressures of pure A and B are 55 and 15 kN m ⁻² respectively. What is the mole fraction of A in so

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19

A solution is prepared by dissolving 0.3 g of a non-volatile non-electrolyte solute 'A' of molar mass 60 ~g ~mol ⁻¹ and 0.9 g of a non-volatile non-electrolyte solute ' B ' of mola

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20

' W ' g of a non-volatile electrolyte solid solute of molar mass ' M ' g mol ⁻¹ when dissolved in 100 mL water, decreases vapour pressure of water from 640 mm Hg to 600 mm Hg. If a

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21

Two liquids A and B form an ideal solution. At 320 K, the vapour pressure of the solution, containing 3 mol of A and 1 mol of B is 500 mm Hg. At the same temperature, if 1 mol of A

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22

Which one of the following graphs accurately represents the plot of partial pressure of CS ₂ vs its mole fraction in a mixture of acetone and CS ₂ at constant temperature?

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23

At T ( K ), 100 ~g of 98 % H ₂ SO ₄( w / w ) aqueous solution is mixed with 100 g of 49 % H ₂ SO ₄( w / w ) aqueous solution. What is the mole fraction of H ₂ SO ₄ in the resultant

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24

Consider a solution of CO ₂( ~g ) dissolved in water in a closed container. Which one of the following plots correctly represents variation of log (partial pressure of CO ₂ in vapo

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25

Given below are two statements: Statement I : The Henry's law constant K _ H is constant with respect to variations in solution's concentration over the range for which the solutio

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26

A substance ' X ' (1.5 g) dissolved in 150 g of a solvent ' Y ' (molar mass =300 ~g ~mol ⁻¹ ) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour

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27

The osmotic pressure of a living cell is 12 atm at 300 K. The strength of sodium chloride solution that is isotonic with the living cell at this temperature is _ _ _ _ g L ⁻¹ . (Ne

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28

Elements P and Q form two types of non-volatile, non-ionizable compounds PQ and PQ ₂ . When 1 g of PQ is dissolved in 50 g of solvent ^ A ^ , T _ b was 1.176 K while when 1 g of PQ

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29

At 300 K , an ideal dilute solution of a macromolecule exerts osmotic pressure that is expressed in terms of the height ( h ) of the solution (density =1.00 ~g ~cm ⁻³ ) where h is

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30

Which of the following binary mixture does not show the behaviour of minimum boiling azeotropes?

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31

Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350 and 750 mm Hg respectively at the same temperature. If x _ A and x_B are the mole fractio

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32

Match List-I with List-II array |l|l|l|l| & List-I & & List-II (A) & array l Solution of chloroform and acetone array & (I) & array l Minimum boiling azeotrope array (B) & array l

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33

The percentage dissociation of a salt ( MX ₃ ) solution at given temperature (van't Hoff factor i = 2) is ______ % (Nearest integer)

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34

Sea water, which can be considered as a 6 molar (6 M ) solution of NaCl , has a density of 2 ~g ~mL ⁻¹ . The concentration of dissolved oxygen ( O ₂ ) in sea water is 5.8 ppm. Then

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35

Given below are two statements : Statement (I) : Molal depression constant K _ f is given by M₁ R T_f S_ f u s , where symbols have their usual meaning. Statement (II) : K _ f for

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36

X Y is the membrane / partition between two chambers 1 and 2 containing sugar solutions of concentration c₁ and c₂ (c₁ c₂ ) mol L ⁻¹ . For the reverse osmosis to take place identif

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37

2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling point of the resulting solution is : (Given : Ebullioscopic constant of water .=0.52 ~K ~kg

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38

When 1 g each of compounds AB and AB ₂ are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (i

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39

' x ' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised from 1^ C to 25^ C . Which out of the following plots, is best suited for the chan

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40

A solution is made by mixing one mole of volatile liquid (A ) with 3 moles of volatile liquid (B ). The vapour pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg

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41

Which of the following graph correctly represents the plots of ( K _ H ) at 1 bar gases in water versus temperature?

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42

Given below are two statements : Statement (I) : NaCl is added to the ice at 0^ C , present in the ice cream box to prevent the melting of ice cream. Statement (II) : On addition o

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43

1.24 g of ( AX ₂ ) (molar mass (124 ~g ~mol ⁻¹ ) ) is dissolved in 1 kg of water to form a solution with boiling point of (100.0156^ C ), while (25.4 ~g ^ ) of ( AY ₂ ) (molar mass

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44

If (A₂ B ) is (30 % ) ionised in an aqueous solution, then the value of van't Hoff factor (i) is ______ ( 10⁻¹ ).

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45

Assume a living cell with 0.9 %( / ) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data up

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46

What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non volatile solute (molar mass 256 ~g ~mol ⁻¹ ) and the decrease in freezing point is 0.40 K

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47

The observed and normal molar masses of compound MX ₂ are 65.6 and 164 respectively. The percent degree of ionisation of MX ₂ is %. (Nearest integer)

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48

Consider the given plots of vapour pressure (VP) vs temperature(T/K). Which amongst the following options is correct graphical representation showing T _ f , depression in the free

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49

Consider a binary solution of two volatile liquid components 1 and 2 . x₁ and y₁ are the mole fractions of component 1 in liquid and vapour phase, respectively. The slope and inter

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50

When a non-volatile solute is added to the solvent, the vapour pressure of the solvent decreases by 10 mm of Hg . The mole fraction of the solute in the solution is 0.2 . What woul

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51

Arrange the following solutions in order of their increasing boiling points. (i) 10⁻⁴ M~ NaCl (ii) 10⁻⁴ M~ Urea (iii) 10⁻³ M~ NaCl (iv) 10⁻² M~ NaCl

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52

Vessel-1 contains w ₂ ~g of a non-volatile solute X dissolved in w ₁ ~g of water. Vessel- 2 contains w ₂ ~g of another non-volatile solute Y dissolved in w ₁ ~g of water. Both the

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53

The vapour pressure of pure benzene and methyl benzene at (27^ C ) is given as 80 Torr and 24 Torr, respectively. The mole fraction of methyl benzene in vapour phase, in equilibriu

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54

A solution is prepared by adding 1 mole ethyl alcohol in 9 mole water. The mass percent of solute in the solution is ________ (Integer answer) (Given : Molar mass in ( g mol ⁻¹ ) E

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55

Molality of an aqueous solution of urea is (4.44 ~m ). Mole fraction of urea in solution is (x 10⁻³ ). Value of (x ) is ( ) - (Integer answer)

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56

A solution containing (10 ~g ) of an electrolyte ( AB ₂ ) in (100 ~g ) of water boils at (100.52^ C ). The degree of ionization of the electrolyte (( ) ) is _______ ( 10⁻¹ ). (near

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57

When ' (x ) ' ( 10⁻² ~mL ) methanol (molar mass (=32 ~g ); density (=0.792 ~g / cm ^3 )) is added to (100 ~mL ) water (density (=1 ~g / cm ^3 )), the following diagram is obtained.

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58

Given below are two statements: Statement I : Gallium is used in the manufacturing of thermometers. Statement II : A thermometer containing gallium is useful for measuring the free

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59

Consider the dissociation of the weak acid ( HX ) as given below ( HX ( aq ) H ⁺( aq )+ X ⁻( aq ), Ka =1.2 10⁻⁵ ) ( [ K _ a . ) : dissociation constant (] ) The osmotic pressure of

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60

Considering acetic acid dissociates in water, its dissociation constant is (6.25 10⁻⁵ ). If (5 ~mL ) of acetic acid is dissolved in 1 litre water, the solution will freeze at (-x 1

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61

An artificial cell is made by encapsulating (0.2 M ) glucose solution within a semipermeable membrane. The osmotic pressure developed when the artificial cell is placed within a (0

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62

(2.7 ~kg ) of each of water and acetic acid are mixed. The freezing point of the solution will be (-x^ C ). Consider the acetic acid does not dimerise in water, nor dissociates in

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63

The Molarity (( M ) ) of an aqueous solution containing (5.85 ~g ) of NaCl in (500 ~mL ) water is : (Given : Molar Mass ( Na : 23 ) and ( Cl : 35.5 gmol ⁻¹ ) )

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64

(2.5 ~g ) of a non-volatile, non-electrolyte is dissolved in (100 ~g ) of water at (25^ C ). The solution showed a boiling point elevation by (2^ C ). Assuming the solute concentra

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65

Mass of ethylene glycol (antifreeze) to be added to 18 . 6 kg of water to protect the freezing point at - 24 ° C is kg (Molar mass in gmol - 1 for ethylene glycol 62 , K f of water

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66

We have three aqueous solutions of NaCl labelled as ‘ A ’ , ‘ B ’ and ‘ C ’ with concentration 0 . 1 M , 0 . 01 M and 0 . 001 M , respectively. The value of van t ’ Haft factor i f

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67

Identify the mixture that shows positive deviations from Raoult's Law

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68

If a substance ' A ' dissolves in solution of a mixture of ' B ' and ' C ' with their respective number of moles as n A , n B and n C , mole fraction of C in the solution is:

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69

The solution from the following with highest depression in freezing point/lowest freezing point is

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70

What happens to freezing point of benzene when small quantity of napthalene is added to benzene?

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71

The mass of sodium acetate CH 3 COONa required to prepare 250 mL of 0 . 35 M aqueous solution is _____ g. Molar mass of CH 3 COONa is 82 . 02 g mol - 1 ) Round off to the nearest i

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72

Molality of 0 . 8 M H 2 SO 4 solution (density 1 . 06 g cm - 3 ) is _______ × 10 - 3 m . Round off your answer to the nearest integer.

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73

A solution of H 2 SO 4 is 31 . 4 % H 2 SO 4 by mass and has a density of 1 . 25 g / mL . The molarity of the H 2 SO 4 solution is M (nearest integer) [Given molar mass of H 2 SO 4

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74

The osmotic pressure of a dilute solution is 7 × 10 5 Pa at 273 K . Osmotic pressure of the same solution at 283 K is _ _ _ _ _ _ _ × 10 4 Nm - 2 .(Nearest integer)

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75

The quantity which changes with temperature is:

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76

A solution of two miscible liquids showing negative deviation from Raoult's law will have :

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77

50 mL of 0 . 2 molal urea solution (density = 1 . 012 g mL - 1 at 300 K ) is mixed with 250 mL of a solution containing 0 . 06 g of urea. Both the solutions were prepared in the sa

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78

The vapour pressure of 30 % w / v , aqueous solution of glucose is ________ mm Hg at 25 ∘ C . [Given: The density of 30 % w / v , aqueous solution of glucose is 1 . 2 g cm &#

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79

Sea water contains 29 . 25 % NaCl and 19 % MgCl 2 by weight of solution. The normal boiling point of the sea water is C ∘ (Nearest integer) Assume 100 % ionization for both N

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80

Solution of 12 g of non-electrolyte (A) prepared by dissolving it in 1000 mL of water exerts the same osmotic pressure as that of 0 . 05 M glucose solution at the same temperature.

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81

80 mole percent of MgCl 2 is dissociated in aqueous solution. The vapour pressure of 1 . 0 molal aqueous solution of MgCl 2 at 38 o C is _____ mm Hg . (Nearest integer) Given: Vapo

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82

What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by 0 . 20 mm Hg ? (Assume dilute solution is being formed) Given: Vapour pressure of pure wa

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83

0 . 004 M K 2 SO 4 solution is isotonic with 0 . 01 M glucose solution. Percentage dissociation of K 2 SO 4 is _____ (Nearest integer)

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84

An aqueous solution of volume 300 cm 3 contains 0 . 63 g of protein. The osmotic pressure of the solution at 300 K is 1 . 29 mbar . The molar mass of the protein is gmol - 1 . Give

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85

If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0 . 3 , then the observed freezing point will be _____ % higher than the expected/theor

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86

If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2: 1 and their enthalpy of vaporizations are in the ratio 1 : 2 , then the boiling po

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87

The vapour pressure vs. temperature curve for a solution solvent system is shown below. The boiling point of the solvent is _____°C.

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88

Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs of solutions is/ are _____ A. 1 M aq . NaCl and 2 M aq . urea B. 1 M aq

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89

Mass of Urea NH 2 CONH 2 required to be dissolved in 1000 g of water in order to reduce the vapour pressure of water by 25 % is _______ g . (Nearest integer) Given : Molar mass of

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90

20 % of acetic acid is dissociated when its 5   g is added to 500   mL of water. The depression in freezing point of such water is _ _ _ _ _ × 10 - 3 C ∘ . Ato

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91

25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO 3 solution when titrated using K 2 CrO 4 as an indicator. What is the depression in freezing point of KCl

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92

Evaluate the following statements for their correctness. A. The elevation in boiling point temperature of water will be same for 0 . 1 M NaCl and 0 . 1 M urea. B. Azeotropic mixtur

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93

The total pressure of a mixture of non-reacting gases X ( 0 . 6 g ) and Y ( 0 . 45 g ) in a vessel is 740 mm of Hg . The partial pressure of the gas X is mm of Hg . (Nearest Intege

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94

At 27 ° C , a solution containing 2 . 5 g of solute in 250 . 0 mL of solution exerts an osmotic pressure of 400 Pa . The molar mass of the solute is g mol - 1 (Nearest integer

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95

Lead storage battery contains 38 % by weight solution of H 2 SO 4 . The van't Hoff factor is 2 . 67 at this concentration. The temperature in Kelvin at which the solution in th

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96

A 300 mL bottle of soft drink has 0 . 2 MCO 2 dissolved in it. Assuming CO 2 behaves as an ideal gas, the volume of the dissolved CO 2 at STP is _____ mL . (Nearest integer) Given:

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97

A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373 . 52 K . The molecular mass of the solute is _____ gmol - 1 . (Nearest integer) Given, water boils

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98

Some amount of dichloromethane CH 2 Cl 2 is added to 671 . 141 mL of chloroform CHCl 3 to prepare 2 . 6 × 10 - 3 M solution of CH 2 Cl 2 DCM . The concentration of DCM is ____

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99

Match List I with List II. List I List II A. van't Hoff factor, i I. Cryoscopic constant B. k f II. Isotonic solutions C. Solutions with same osmotic pressure III. Normal molar

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100

Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at 100 . 15 ° C . When 0 . 2 mol of NaCl is added to the resulting solution, it was observe

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101

What is the mass ratio of ethylene glycol ( C 2 H 6 O 2 , molar mass = 62 g / mol ) required for making 500 g of 0 . 25 molal aqueous solution and 250 mL of 0 . 25 molar aqueous so

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102

The number of pairs of the solution having the same value of the osmotic pressure from the following is (Assume 100 % ionization) A. 0 . 500   M   C 2 H 5 OH ( aq ) and 0

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103

The osmotic pressure of solutions of PVC in cyclohexanone at 300 K are plotted on the graph. The molar mass of PVC is g mol - 1 (Nearest integer) (Given : R = 0 . 083 L atm K - 1 m

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104

The Total pressure observed by mixing two liquid A and B is 350 mm Hg when their mole fractions are 0 . 7 and 0 . 3 respectively. The Total pressure becomes 410 mm Hg if the mole f

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105

The number of units, which are used to express concentration of solutions from the following is _________. (Mass percent, Mole, Mole fraction, Molarity, ppm, Molality.)

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106

In the depression of freezing point experiment A. Vapour pressure of the solution is less than that of pure solvent B. Vapour pressure of the solution is more than that of pure sol

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107

When Fe 0 . 93 O is heated in presence of oxygen, it converts to Fe 2 O 3 . The number of correct statement/s from the following is ______ . A. The equivalent weight of Fe 0 . 93 O

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108

5 g of NaOH was dissolved in deionized water to prepare a 450 mL stock solution. What volume (in mL) of this solution would be required to prepare 500 mL of 0 . 1 M solution ? Give

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109

An aqueous solution is prepared by dissolving 0 . 1 mole of an ionic salt in 1 . 8 kg of water at 35 ° C . The salt remains 90 % dissociated in the solution. The vapour pressu

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110

' x ' g of molecular oxygen O 2 is mixed with 200 g of neon Ne . The total pressure of the nonreactive mixture of O 2 and Ne in the cylinder is 25 bar. The partial pressure

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111

1 . 80   g of solute A was dissolved in 62 . 5   cm 3 of ethanol and freezing point of the solution was found to be 155 . 1   K . The molar mass of solute A is gmol

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112

If O 2 gas is bubbled through water at 303 K , the number of millimoles of O 2 gas that dissolve in 1 litre of water is____(Nearest integer) (Given : Henry's Law constant for O

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113

A gaseous mixture of two substances A and B , under a total pressure of 0 . 8 atm is in equilibrium with an ideal liquid solution. The mole fraction of substance A is 0 . 5 in the

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114

150 g of acetic acid was contaminated with 10 . 2 g ascorbic acid C 6 H 8 O 6 to lower down its freezing point by x × 10 - 1 ° C . The value of x is____ (Nearest integer)

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115

When a certain amount of solid A is dissolved in 100   g of water at 25   ° C to make a dilute solution, the vapour pressure of the solution is reduced to one-half o

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116

Boiling point of a 2 % aqueous solution of a nonvolatile solute A is equal to the boiling point of 8 % aqueous solution of a non-volatile solute B . The relation between molecular

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117

The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K . The depression in freezing point for 2 molal solution of A in the same solvent is 6 K . The ra

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118

Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y . respectively in 1 kg of water. The ratio of depression in freezing points for A and B is foun

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119

The depression in freezing point observed for a formic acid solution of concentration 0 . 5 mL L - 1 is 0 . 0405 ° C . Density of formic acid is 1 . 05 g mL - 1 . The Van'

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120

Elevation in boiling point for 1 . 5 molal solution of glucose in water is 4   K . The depression in freezing point for 4 . 5 molal solution of glucose in water is 4   K

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