JEE Advanced2015ChemistrySurface ChemistryActual
When O 2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O 2 . The TRUE statement(s) regarding this adsorption is(are)
Options
- AO 2 is physisorbed
- BHeat is released
- COccupancy of π 2 p * of O 2 is increased
- DBond length of O 2 is increased
Correct answer
B. Heat is released
Step-by-step solution
It is a chemisorption Δ H is - v e for adsorption. Due to electron intake in O 2 molecule π 2 p x * or π 2 p y * (ABMO) will gain electrons and bond order of O 2 molecule (Adsorbed) will decrease and bond length increased.