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Surface Chemistry — JEE Main & Advanced Chemistry PYQs

195 previous year questions from Surface Chemistry with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

At a given temperature, 0.45 g of acetic acid in 50 mL of water is shaken with 1.0 g of charcoal and the pH of the resulting solution is 3.0 . Assume, the adsorption of acetic acid

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2

Adsorption of phenol from its aqueous solution on to fly ash obeys Freundlich isotherm. At a given temperature, from 10 mg g ⁻¹ and 16 mg g ⁻¹ aqueous phenol solutions, the concent

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3

Consider the following statements related to colloids. (I) Lyophobic colloids are not formed by simple mixing of dispersed phase and dispersion medium. (II) For emulsions, both the

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4

20 mL of 0 . 5 M NaCl is required to coagulate 200 mL of As 2 S 3 solution in 2 hours. The coagulating value of NaCl is ___________.

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5

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : The diameter of colloidal particles in solution should not be mu

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6

What happens when a lyophilic sol is added to a lyophobic sol?

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7

Four gases, A , B , C and D have critical temperatures 5 . 3 , 33 . 2 , 126 . 0 and 154 . 3 K respectively For their adsorption on a fixed amount of charcoal, the correct order is

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8

The number of correct statements about modern adsorption theory of heterogeneous catalysis from the following is ...... A. The catalyst is diffused over the surface of reactants. B

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9

Ferric chloride is applied to stop bleeding because

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10

The statement/s which are true about antagonists from the following is/are: A. They bind to the receptor site. B. Get transferred inside the cell for their action. C. Inhibit the n

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11

Coagulating value of the electrolytes AlCl 3 and NaCl tor As 2 S 3 are 0 . 09 and 50 . 04 respectively. The coagulating power of AlCl 3 is x times the coagulating power of NaCl . T

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12

The water gas on reacting with cobalt as a catalyst forms

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13

Which of the following represents the Freundlich adsorption isotherms? (A) (B) (C) (D) Choose the correct answer from the options given below:

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14

The number of colloidal systems from the following, which will have 'liquid' as the dispersion medium, is _____. Gem stones, paints, smoke, cheese, milk, hair cream, insect

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15

Match List I with List II List-I – Enzymatic reaction List-II - Enzyme A Sucrose→ Glucose and Fructose I Zymase B Glucose → ethyl alcohol and CO 2 II Pepsin C Starc

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16

In figure, a straight line is given for Freundrich Adsorption ( y = 3 x + 2 . 505 ) . The value of 1 n and logK are respectively.

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17

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R. Assertion A: Amongst He , Ne , Ar and Kr ; 1 g of activated charcoal adsorbs m

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18

Match List I with List II List I List II A Physisorption I Single Layer Adsorption B Chemisorption II 20 - 40 kJ mol - 1 C N 2 g + 3 H 2 g ⟶ Fe ( s ) 2 NH 3 g III Chromatogr

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19

Adding surfactants in non polar solvent, the micelles structure will look like (a) (b) (c) (d)

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20

The graph of log x m vs log p for an adsorption process is a straight line inclined at an angle of 45 ° with intercept equal to 0 . 6020 . The mass of gas adsorbed per unit ma

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21

Match List-I and List-II List-I List-II A. Osmosis I. Solvent molecules pass through semi permeable membrane towards solvent side. B. Reverse osmosis II. Movement of charged colloi

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22

Which of the following salt solutions would coagulate the colloid soloution formed when FeCl 3 is added to NaOH solution, at the fastest rate?

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23

Based on the given figure, the number of correct statement/s is/are A. Surface tension is the outcome of equal attractive and repulsion forces acting on the liquid molecule in bulk

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24

The number of incorrect statement/s from the following is/are A. Water vapours are adsorbed by anhydrous calcium chloride. B. There is a decrease in surface energy during adsorptio

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25

The number of statement/s which are the characteristics of physisorption is ___________. A. It is highly specific in nature B. Enthalpy of adsorption is high C. It decreases with i

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26

Statement I: For colloidal particles, the values of colligative properties are of small order as compared to values shown by true solutions at same concentration. Statement II: For

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27

The correct option(s) related to adsorption processes is(are)

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28

Given below are the critical temperatures of some of the gases: Gas Critical temperature K He 5 . 2 CH 4 190 CO 2 304 . 2 NH 3 405 . 5 The gas showing least adsorption on a definit

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29

100 mL of 5 % w / v solution of NaCl in water was prepared in 250 mL beaker. Albumin from the egg was poured into NaCl solution and stirred well. This resulted in a/ an

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30

Among the following the number of curves not in accordance with Freundlich adsorption isotherm is

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31

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R Assertion A : Dissolved substances can be removed from a colloidal solution by

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32

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R . Assertion A : Finest gold is red in colour, as the size of the particles incr

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33

Match List - I with List - II. List –I (Processes/Reactions) List-II (Catalyst) A 2 SO 2 g + O 2 g → 2 SO 3 g I Fe s B 4 NH 3 g + 5 O 2 g → 4 NO g + 6 H 2 O g II

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34

For micelle formation, which of the following statements are correct? (A) Micelle formation is an exothermic process. (B) Micelle formation is an endothermic process. (C) The entro

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35

42 . 12 % (w/v) solution of NaCl causes precipitation of a certain sol in 10 hours. The coagulating value of NaCl for the sol is [Given : Molar mass : Na = 23 . 0 g mol - 1 ; Cl =

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36

Which of the following is a correct statement?

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37

Match List-I with List-II List-I List-II (A) negatively charged sol (I) Fe 2 O 3 · xH 2 O (B) macromolecular colloid (II) CdS sol (C) positively charged sol (III) Starch (D) C

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38

The Zeta potential is related to which property of colloids?

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39

If the initial pressure of a gas is 0 . 03 atm , the mass of the gas adsorbed per gram of the adsorbent is____ × 10 - 2 g

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40

Match List - I with List - II. List-I List-II A Lyophilic colloid I Liquid-liquid colloid B Emulsion II Protective colloid C Positively charged colloid III FeCl 3 + NaOH D Negative

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41

2 . 0   g of H 2   gas is adsorbed on 2 . 5   g of platinum powder at 300   K and 1 bar pressure. The volume of the gas adsorbed per gram of the adsorbent is mL

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42

Incorrect statement for Tyndall effect is

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43

When 200   mL of 0 . 2   M acetic acid is shaken with 0 . 6   g of wood charcoal, the final concentration of acetic acid after adsorption is 0 . 1   M . The mas

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44

Given below are two statements: Statement I : Emulsions of oil in water are unstable and sometimes they separate into two layers on standing. Statement II : For stabilisation of an

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45

The correct statement s related to colloids is(are)

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46

Match List - I with List - II . List- I (Colloid Preparation Method) List- II (Chemical Reaction) ( a ) Hydrolysis ( i ) 2 AuCl 3 + 3 HCHO + 3 H 2 O → 2 Au ( sol ) + 3 HCOOH

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47

CH 4 is adsorbed on 1 g charcoal at 0 ° C following the Freundlich adsorption isotherm. 10 . 0 mL of CH 4 is adsorbed at 100 mm of Hg , whereas 15 . 0 mL is adsorbed at 200 mm

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48

Select the graph that correctly describes the adsorption isotherms at two temperatures T 1 and T 2 T 1 > T 2 for a gas : ( x - mass of the gas adsorbed m - - mass of adsorbent

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49

Lyophilic sols are more stable than lyophobic sols because:

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50

Tyndall effect is more effectively shown by:

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51

The sol given below with negatively charged colloidal particles is:

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52

Which one of the following is correct for the adsorption of a gas at a given temperature on a solid surface?

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53

Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R . Assertion A : SO 2 ( g ) is adsorbed to a large extent than H 2 ( g ) on acti

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54

CO 2 gas adsorbs on charcoal following Freundlich adsorption isotherm. For a given amount of charcoal, the mass of CO 2 adsorbed becomes 64 times when the pressure of CO 2 is doubl

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55

Match List I with List II : List-I List-II Example of colloids Classification (a) Cheese (i) dispersion of liquid in liquid (b) Pumice stone (ii) dispersion of liquid in gas (c) Ha

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56

When silver nitrate solution is added to potassium iodide solution then the sol produced is:

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57

For coagulation of 50 mL of a sol, 10 mL of 0.5M Cl - ion solution is required. What is the coagulating value of Cl - ion solution (Nearest integer) NOTE: NTA question has been cha

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58

The conditions given below are in the context of observing Tyndall effect in colloidal solutions: (A) The diameter of the colloidal particles is comparable to the wavelength of lig

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59

The charges on the colloidal CdS sol and TiO 2 sol are, respectively :

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60

For the coagulation of a negative sol, the species below, that has the highest flocculating power is:

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61

A colloidal system consisting of a gas dispersed in a solid is called a/an:

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62

The INCORRECT statements below regarding colloidal solutions is :

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63

The nature of charge on resulting colloidal particles when FeCl 3 is added to excess of hot water is:

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64

3 . 12   g of oxygen is adsorbed on 1 . 2   g of platinum metal. The volume of oxygen adsorbed per gram of the adsorbent at 1   atm and 300   K in L is R = 0 .

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65

Which one of the following statements is FALSE for hydrophilic sols?

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66

In Freundlich adsorption isotherm at moderate pressure, the extent of adsorption x m is directly proportional to P x . The value of x is :

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67

Most suitable salt which can be used for efficient clotting of blood will be?

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68

In Freundlich adsorption isotherm, slope of AB line is:

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69

For Freundlich adsorption isotherm, a plot of log x / m y - axis and log p x - axis gives a straight line, the intercept and slope fo rthe line is 0 . 4771 and 2 , respectively. Th

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70

Kraft temperature is the temperature:

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71

Adsorption of a gas follows Freudlich adsorption isotherm. If x is the mass of the gas adsorbed on mass m of the adsorbent, the correct plot of x m versus p is:

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72

Identify the correct molecular picture showing what happens at the critical micellar concentration ( CMC ) of an aqueous solution of a surfactant

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73

A sample of red ink (a colloidal suspension) is prepared by mixing eosine dye, egg white, HCHO and water. The component which ensures stability of the ink sample is :

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74

Match the following: (i) Foam (a) smoke (ii) Gel (b) cell fluid (iii) Aerosol (c) jellies (iv) Emulsion (d) rubber (e) froth (f) milk

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75

Tyndall effect is observed when :

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76

Amongst the following statements regarding adsorption, those that are valid are: (a) Δ H becomes less negative as adsorption proceeds. (b) On a given adsorbent, ammonia is ads

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77

Which of the following is used for the preparation of colloids ?

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78

The mass of gas adsorbed, x , per unit mass of adsorbate, m , was measured at various pressures, p . A graph between log x m and log p gives a straight line with slope equal to 2 a

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79

As per Hardy-Schulze formulation, the flocculation values of the following for ferric hydroxide sol are in the order:

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80

The flocculation value of H C l for arsenic sulphide s o l is 30 m m o l L - 1 . If H 2 S O 4 is used for the flocculation of arsenic sulphide, the amount, in grams, of H 2 S O 4 i

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81

The critical micelle concentration CMC of a cationic colloidal electrolyte is 10 - 3 M . If 1 mm 3 contains 10 13 micelles, the number of cations making one micelle is (Given, N A

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82

The coagulation of 10 cm 3 of Gold sol by 1 ml 10% NaCl solution is completely prevented by addition of 0.25 g of starch to it. The gold number of starch is-

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83

Adsorption of a gas follows Freundlich adsorption isotherm. In the given plot, x is the mass of the gas adsorbed on mass m of the adsorbent at pressure (P). if x m ∝ P ( 1 / y ) fi

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84

The gold numbers of a few protective colloids are (A) Starch = 25 (B) Gelatin = 0.005 - 0.01 (C) Hemoglobin = 0.03 (D) ​Dextrin = 6 - 123. Which is the best protective colloid ?

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85

A catalyst adsorb 100 mL of nitrogen gas at S.T.P. per gram of catalyst surface and forms a mono-molecular layer. The effective surface area occupied by one nitrogen molecule on th

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86

Bleeding is stopped by the application of ferric chloride. This is because:

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87

Which of the following is less than zero during adsorption?

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88

A s 2 S 3 and T i O 2 sol are examples of

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89

Which of the following sols is negatively charged?

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90

Graph between log ⁡ x m v s log ⁡ P is provided for adsorption of N H 3 gas on metal surface. Calculate weight of N H 3 gas (in gm) absorbed by 24 g of metal surface at 2 atm press

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91

Among the following, the surface that will form micelles in aqueous solution at the lowest molar concentration at ambient condition is:

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92

Which of the following statements is correct for a lyophilic sol?

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93

100 mL of 0 .3 M acetic acid is shaken with 0 .8 g wood charcoal. The final concentration of acetic acid in the solution after adsorption is 0 .125 M . The mass of acetic acid adso

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94

Adsorption of gases on solid surface is generally exothermic because

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95

For coagulation of Arsenious sulphide sol, which one of the following salt solution will be most effective

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96

5 ml of A s 2 S 3 is mixed with distilled waterand 0 .01 M solution of an electrolyte AB so that total volume is 10 ml . it was found that all solution containing more than 5 ml of

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97

The coagulation values in millimoles per litre of the electrolytes used for coagulation of A s 2 S 2 are given below. I. N a C l = 52 II. B a C l 2 = 0.69 III. M g S O 4 = 0.22 The

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98

Which of the following statements about physical adsorption is not correct?

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99

The plots of the extent of adsorption (x/m) Vs pressure at different temperature are as follows; The correct order of increasing temp for curves I, II, III, IV are ;

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100

Which of the following is not an example of heterogeneous catalysis?

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101

In the Freundlich adsorption isotherm, the value of 1 n is between 0 and -----.

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102

10 mL of 1 mM surfactant solution forms a monolayer covering 0 . 24 c m 2 on a polar substrate. If the polar head is approximated as cube, what is its edge length?

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103

Rate of reaction (r) is plotted against temperature (T) for an enzyme catalysed reaction. Which of the following is correct representation?

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104

The correct option among the following is

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105

Which of the following electrolytes will have maximum coagulating value for A g I A g + sol?

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106

A graph is plotted between log (x/m) and log P according to the equation x m = k P 1 n . Which of the following statements about this graph is not correct?

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107

Which of the plots is adsorption isobar for chemisorption?

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108

Plot of log x/m against log p is a straight line inclined at an angle of 45 ° . When the pressure is 0.5 atm and Freundlich parameter, k is 10, the amount of soluble adsorbed per g

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109

Colloidal sulphur is obtained when

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110

The best electrolyte for coagulating A s 2 S 3 sol is

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111

The degree of adsorption of solution on solid surface depends on concentration of solution x m = K C 1 n In which of the conditions, we get following type of graph?

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112

Among the following surfactant molecules, the surfactant that forms micelles in aqueous solution at the lower CMC at ambient condition is

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113

Which of the following option is correct for given curve?

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114

The disperse phase in colloidal iron (III) hydroxide and colloidal gold is positively and negatively charged, respectively. Which of the following statements is NOT correct?

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115

Which one is not correct according to Langmuir adsorption isotherm at very high pressure?

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116

Graph between log ⁡ x m and log P is straight line at angle of 45 ° with the intercept of 0.6020. The extent of adsorption x m at a pressure of 1 atm is

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117

How physical adsorption will be effected by increase in temperature

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118

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, C H 3 O H and C H 3 C

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119

For adsorption of a gas on a solid, the plot of log ⁡ x m vs log P is linear with slope equal to (n being whole number)

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120

Select the correct adsorption isobars for chemisorptions and physisorption respectively (Here, x m degree of adsorption)

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