Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 20265 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2026 · 5 April · Morning Shift · Chemistry · Haloalkanes and Haloarenes

Benzyl isocyanide can be obtained from Choose the correct answer...

Benzyl isocyanide can be obtained from
Benzyl isocyanide can be obtained from Choose the correct answer from the options given below:
Choose the correct answer from the options given below:

Options

  1. AA and B Only
  2. BA and C Only
  3. CB and D Only
  4. DD and E Only

Correct answer

A. A and B Only

Step-by-step solution

Reaction A: C6H5CH2Br+AgCN→C6H5CH2NC+AgBrC_6H_5CH_2Br + AgCN \rightarrow C_6H_5CH_2NC + AgBr
AgCNAgCN is predominantly covalent, so the nucleophilic attack occurs through the nitrogen atom, forming benzyl isocyanide.

Reaction B: C6H5CH2NH2+CHCl3+3NaOH→C6H5CH2NC+3NaCl+3H2OC_6H_5CH_2NH_2 + CHCl_3 + 3NaOH \rightarrow C_6H_5CH_2NC + 3NaCl + 3H_2O
This is the carbylamine reaction. Primary amines react with chloroform and alkali to form isocyanides. Benzyl amine gives benzyl isocyanide.

Reaction C: C6H5Br+AgCN→C_6H_5Br + AgCN \rightarrow No reaction
Aryl halides are generally unreactive towards nucleophilic substitution under normal conditions due to the partial double bond character of the C-Br bond.

Reaction D: C6H5NH2+CHCl3+3NaOH→C6H5NC+3NaCl+3H2OC_6H_5NH_2 + CHCl_3 + 3NaOH \rightarrow C_6H_5NC + 3NaCl + 3H_2O
Aniline undergoes the carbylamine reaction to form phenyl isocyanide, not benzyl isocyanide.

Reaction E: C6H5CH2CH2Br+KCN→C6H5CH2CH2CN+KBrC_6H_5CH_2CH_2Br + KCN \rightarrow C_6H_5CH_2CH_2CN + KBr
KCNKCN is predominantly ionic, so the nucleophilic attack occurs through the carbon atom, forming a cyanide (nitrile) rather than an isocyanide.

Thus, benzyl isocyanide is obtained from reactions A and B only.

Answer: A and B Only
Practice Haloalkanes and Haloarenes on Quantrex Academy →

More from Haloalkanes and Haloarenes

n-Butane on monochlorination under photochemical condition gives an optically active… JEE Main 2026Given below are two statements: Statement I: Due to increase in van der Waals forces, the… JEE Main 2026RMgI when treated with ice cold water liberated a gas which occupied 1.4 dm^3/g at STP.… JEE Main 2026Match the LIST-I with LIST-II List-I (Reaction) List-II (Mechanism) A. Williamson… JEE Main 2026Match the LIST-I with LIST-II List-I Name of reaction List-II Reagent or catalyst used A.… JEE Main 2026Correct statements regarding alkyl halides (R - X) among the following are: A. Alcohol… JEE Main 2026Given below are two statements : Statement (I) : Benzyl chloride reacts faster in S_N1… JEE Main 2026Which of the following reaction is NOT correctly represented? JEE Main 2026 Full Haloalkanes and Haloarenes list All JEE Main PYQs