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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Haloalkanes and Haloarenes

JEE Main 2026 · 2 April · Evening Shift · Chemistry · Haloalkanes and Haloarenes

Correct statements regarding alkyl halides (R - X) among the...

Correct statements regarding alkyl halides (R−X)(R - X) among the following are:
A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R−XR - X.
B. Order of reactivity towards SN1S_N^1 mechanism is C6H5−CH2−Cl>C6H5−CHCl−C6H5C_6 H_5 - CH_2 - Cl > C_6 H_5 - CHCl - C_6 H_5.
C. Non substituted aryl halides exhibit properties similar to alkyl halides.
D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne.
E. R−ClR - Cl can be prepared by reacting R−OHR - OH with SOCl2SOCl_2 but Ar−ClAr - Cl cannot be prepared by reacting Ar−OHAr - OH with SOCl2SOCl_2.
Choose the correct answer from the options given below:

Options

  1. AA, B and C Only
  2. BB and D Only
  3. CA and E Only
  4. DD and E Only

Correct answer

C. A and E Only

Step-by-step solution

Statement A is correct. Alcoholic KOH provides alkoxide ions which are stronger bases than hydroxide ions. Furthermore, alcohol is a less polar solvent than water, which decreases the solvation of the base, making it more effective for elimination reactions over substitution.

Statement B is incorrect. The reactivity towards the SN1S_N^1 mechanism depends on the stability of the intermediate carbocation. The carbocation C6H5−C+H−C6H5C_6H_5-\overset{+}{C}H-C_6H_5 is more stable than C6H5−C+H2C_6H_5-\overset{+}{C}H_2 due to extended resonance stabilization from two phenyl rings. Thus, C6H5−CHCl−C6H5C_6H_5-CHCl-C_6H_5 is more reactive than C6H5−CH2−ClC_6H_5-CH_2-Cl.

Statement C is incorrect. Aryl halides are much less reactive towards nucleophilic substitution than alkyl halides due to the partial double bond character of the C-X bond arising from resonance, as well as the sp2sp^2 hybridization of the carbon atom.

Statement D is incorrect. Allyl chloride (CH2=CH−CH2−ClCH_2=CH-CH_2-Cl) contains a carbon-carbon double bond, making it a haloalkene, not a haloalkyne.

Statement E is correct. Alkyl chlorides (R−ClR-Cl) can be easily prepared from alcohols (R−OHR-OH) using SOCl2SOCl_2. However, phenols (Ar−OHAr-OH) do not react with SOCl2SOCl_2 to give aryl chlorides because the C-O bond in phenol has a partial double bond character due to resonance, making it difficult to cleave.

Therefore, only statements A and E are correct.

Answer: A and E Only
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