JEE Main20262 April 2026Evening ShiftChemistryHaloalkanes and HaloarenesActual
Correct statements regarding alkyl halides (R - X) among the following are: A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R - X . B. Order of reactivity towards S_N^1 mechanism is C₆ H₅ - CH₂ - Cl > C₆ H₅ - CHCl - C₆ H₅ . C. Non substituted aryl halides exhibit properties similar to alkyl halides. D. Vinyl chloride is an example of haloalkene and allyl chlor
Options
- AA, B and C Only
- BB and D Only
- CA and E Only
- DD and E Only
Correct answer
C. A and E Only
Step-by-step solution
Statement A is correct. Alcoholic KOH provides alkoxide ions which are stronger bases than hydroxide ions. Furthermore, alcohol is a less polar solvent than water, which decreases the solvation of the base, making it more effective for elimination reactions over substitution. Statement B is incorrect. The reactivity towards the S_N^1 mechanism depends on the stability of the intermediate carbocation. The carbocation C₆H₅- + C H-C₆H₅ is more stable than C₆H₅- + C H₂ due to extended resonance stabilization from two p