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JEE Main
Exam
JEE Main
Subject
Physics
Chapter
Kinetic Theory of Gases

JEE Main · Physics · Kinetic Theory of Gases

A cylinder consists of a gas mixture of helium and oxygen. If the...

A cylinder consists of a gas mixture of helium and oxygen. If the mass of helium is 4 g4 \mathrm{~g} and the mass of oxygen is 32 g32 \mathrm{~g}, then the ratio of specific heat of the mixture (Cp/CV)\left(C_p / C_V\right)

Options

  1. A2/3
  2. B3/2
  3. C1/2
  4. D1/3

Correct answer

B. 3/2

Step-by-step solution

Mass of helium, mHe=4 gm_{\mathrm{He}}=4 \mathrm{~g} Mass of oxygen, mO=32 gm_{\mathrm{O}}=32 \mathrm{~g} Helium is a monoatomic gas. ∴\therefore Degrees of freedom, f1=3f_1=3 Oxygen is a diatomic gas. ∴\therefore Degrees of freedom, f2=54 gf_2=54 \mathrm{~g} helium contains N1=NA=6.023×1023N_1=N_A=6.023 \times 10^{23} number of molecules 32 g32 \mathrm{~g} oxygen contains N2=NAN_2=N_A number of molecules. (As atomic mass of oxygen is 16 g16 \mathrm{~g} ) ∴CpCV=γ=N1(2+f1)+N2(2+f2)N1f1+N2f2=NA(2+3)+NA(2+5)3NA+5NA=5+73+5=128=32\begin{aligned} \therefore \quad\frac{C_p}{C_V}& =\gamma\\ & =\frac{N_1\left(2+f_1\right)+N_2\left(2+f_2\right)}{N_1 f_1+N_2 f_2}\\ & =\frac{N_A(2+3)+N_A(2+5)}{3 N_A+5 N_A}\\ & =\frac{5+7}{3+5}=\frac{12}{8}=\frac{3}{2} \end{aligned}
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