JEE Main 20266 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 6 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Hydrocarbons
JEE Main 2026 · 6 April · Evening Shift · Chemistry · Hydrocarbons
An optically active alkyl bromide C _4 H _9 Br, reacts with...
An optically active alkyl bromide CHBr, reacts with ethanolic KOH to form major compound [A] which reacts with bromine to give compound [B]. Compound [B] reacts with ethanolic KOH and sodamide to give compound [C]. One molecule of water adds to compound [C] on warming with mercuric sulphate and dilute sulphuric acid at K to form compound [D]. The functional group in compound D will be confirmed by :
Options
- AHaloform test
- BLucas test
- CSilver mirror test
- DBenedict test
Correct answer
A. Haloform test
Step-by-step solution
The optically active alkyl bromide is -bromobutane, .
Reaction with ethanolic undergoes dehydrohalogenation to form but--ene as the major product [A] (Zaitsev's rule).
But--ene [A] reacts with to form -dibromobutane [B], .
Compound [B] undergoes double dehydrohalogenation with ethanolic and to give but--yne [C], .
Hydration of but--yne [C] with and dilute yields butan--one [D], .
Since compound [D] is a methyl ketone, its functional group is confirmed by the haloform test.
Answer: Haloform test
Reaction with ethanolic undergoes dehydrohalogenation to form but--ene as the major product [A] (Zaitsev's rule).
But--ene [A] reacts with to form -dibromobutane [B], .
Compound [B] undergoes double dehydrohalogenation with ethanolic and to give but--yne [C], .
Hydration of but--yne [C] with and dilute yields butan--one [D], .
Since compound [D] is a methyl ketone, its functional group is confirmed by the haloform test.
Answer: Haloform test