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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Specific Heat Capacities of Gases

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Specific Heat Capacities of Gases

An ideal gas expands from 100 cm^3 to 200 cm^3 at a constant...

An ideal gas expands from 100 cm3100 \text{ cm}^3 to 200 cm3200 \text{ cm}^3 at a constant pressure of 2.0×105 Pa2.0 \times 10^5 \text{ Pa} when 50 J50 \text{ J} of heat is supplied to it. Assuming the initial temperature is 300 K300 \text{ K}, calculate the molar heat capacity CVC_V at constant volume.

Options

  1. A12.5 J K−1 mol−112.5 \text{ J K}^{-1} \text{ mol}^{-1}
  2. B20.8 J K−1 mol−120.8 \text{ J K}^{-1} \text{ mol}^{-1}
  3. C16.6 J K−1 mol−116.6 \text{ J K}^{-1} \text{ mol}^{-1}
  4. D4.16 J K−1 mol−14.16 \text{ J K}^{-1} \text{ mol}^{-1}

Correct answer

A. 12.5 J K−1 mol−112.5 \text{ J K}^{-1} \text{ mol}^{-1}

Step-by-step solution

Work done by the gas is given by:

ΔW=PΔV=2.0×105×(200−100)×10−6=20 J\Delta W = P \Delta V = 2.0 \times 10^5 \times (200 - 100) \times 10^{-6} = 20 \text{ J}

From the first law of thermodynamics:

ΔQ=ΔU+ΔW\Delta Q = \Delta U + \Delta W

50=ΔU+20⇒ΔU=30 J50 = \Delta U + 20 \Rightarrow \Delta U = 30 \text{ J}

The change in internal energy is:

ΔU=nCVΔT\Delta U = n C_V \Delta T

For an isobaric process, the ideal gas equation gives PΔV=nRΔTP \Delta V = n R \Delta T. Thus:

nΔT=PΔVR=20Rn \Delta T = \dfrac{P \Delta V}{R} = \dfrac{20}{R}

Substituting this into the equation for ΔU\Delta U:

30=CV30 = C_V\left( \dfrac{20}{R} \right)<br><br>C_V = 30R20=\dfrac{30 R}{20} =1.5 R<br><br>Usingtheuniversalgasconstant<br><br>Using the universal gas constantR = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}:<br><br>:<br><br>C_V = 1.5 \times 8.314 \approx 12.5 \text{ J K}^{-1} \text{ mol}^{-1}
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