Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 20241 FebruaryEvening Shift
Exam
JEE Main
Year
2024
Date
1 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2024 · 1 February · Evening Shift · Chemistry · Ionic Equilibrium

Solubility of calcium phosphate (molecular mass, M ) in water is W...

Solubility of calcium phosphate (molecular mass, MM) in water is Wg{W}_{g} per 100mL100mL at 25°C.25 ° C . Its solubility product at 25°C25 ° C will be approximately.

Options

  1. A{10}^{7}{\left(\dfrac{W}{M}\right)}^{3}
  2. B{10}^{7}{\left(\dfrac{W}{M}\right)}^{5}
  3. C{10}^{3}{\left(\dfrac{W}{M}\right)}^{5}
  4. D{10}^{5}{\left(\dfrac{W}{M}\right)}^{5}

Correct answer

B. {10}^{7}{\left(\dfrac{W}{M}\right)}^{5}

Step-by-step solution

Given the solubility of Ca3(PO4)2{Ca}_{3}{\left({PO}_{4}\right)}_{2} is Wg/100mLWg / 100mL. The solubility in mol/Lmol / L is S=WM×1000100mol/LS = \dfrac{W}{M} \times \dfrac{1000}{100}mol / L.

The equilibrium reaction of calcium phosphate is 

{Ca3(PO4)2⇌3Ca2++2PO43−Atequilibrium3S2S\begin{cases} & {Ca}_{3}{\left({PO}_{4}\right)}_{2} & \overset{}{⇌} & 3{Ca}^{2 +} & + & 2{PO}_{4}^{3 -} \\ Atequilibrium & & & 3S & & 2S\end{cases}

Now, Ksp=[Ca2+]3[PO43−]2{K}_{sp} = {\left[{Ca}^{2 +}\right]}^{3}{\left[{PO}_{4}^{3 -}\right]}^{2}

⇒Ksp=(3S)3(2S)2=108×S5⇒ {K}_{sp} = {\left(3S\right)}^{3}{\left(2S\right)}^{2} = 108 \times {S}^{5}

⇒Ksp=108×(WM×10)5⇒Ksp=108×105×(WM)5⇒ {K}_{sp} = 108 \times {\left(\dfrac{W}{M} \times 10\right)}^{5} ⇒ {K}_{sp} = 108 \times {10}^{5} \times {\left(\dfrac{W}{M}\right)}^{5}

=1.08×107(WM)5= 1 . 08 \times {10}^{7}{\left(\dfrac{W}{M}\right)}^{5}

Practice Ionic Equilibrium on Quantrex Academy →

More from Ionic Equilibrium

Given is a concentrated solution of a weak electrolyte A_xB_y of concentration 'c' and… JEE Main 2026M_3 A_2 is a sparingly soluble salt of molar mass y g mol ^ -1 and solubility x g L ^ -1… JEE Main 2026Arrange the following resultant mixtures in increasing order of their pH values A. 10 mL… JEE Main 202620 mL of a solution of acetic acid required 28.4 mL of 0.1 M NaOH for its neutralization.… JEE Main 2026The pH of a solution obtained by mixing 5 mL of 0.1 M NH_4OH solution with 250 mL of 0.1… JEE Main 2026The first and second ionization constants of a weak dibasic acid H_2 A are 8.1 × 10^ -8… JEE Main 2026At 25°C , 20.0 mL of 0.2 M weak monoprotic acid HX is titrated against 0.2 M NaOH. The pH… JEE Main 2026The solubility product constants of Ag_2CrO_4 and AgBr are 32x and 4y respectively at 298… JEE Main 2026 Full Ionic Equilibrium list All JEE Main PYQs