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JEE Main 202118 MarchEvening Shift
Exam
JEE Main
Year
2021
Date
18 March
Shift
Evening Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2021 · 18 March · Evening Shift · Chemistry · Ionic Equilibrium

The solubility of CdSO _ 4 in water is 8 . 0 × 10 ^ - 4 mol L ^ - 1...

The solubility of CdSO4{CdSO}_{4} in water is 8.0×10−4molL−18 . 0 \times {10}^{- 4}mol{L}^{- 1}. Its solubility in 0.01MH2SO40 . 01M{H}_{2}{SO}_{4} solution is ___ ×10−6molL−1\times {10}^{- 6}mol{L}^{- 1} (Round off to the Nearest integer) (Assume that solubility is much less than 0.01M0 . 01M )

Correct answer

0

Step-by-step solution

In pure water,

Ksp=S2=(8×10−4)2{K}_{sp} = {S}^{2} = {\left(8 \times {10}^{- 4}\right)}^{2}

=64×10−8= 64 \times {10}^{- 8}

In 0.01MH2SO40 . 01M{H}_{2}{SO}_{4}

H2SO4(aq)x→2H(aq)+x+SO42−(aq.)(x+0.01)\mathop{{H}_{2}{SO}_{4 ( aq )}}_{x} \to \mathop{2{H}_{( aq )}^{+}}_{x} + \mathop{{SO}_{4}^{2 -} ( aq . )}_{( x + 0 . 01 )}

Ksp=x(x+0.01){K}_{sp} = x ( x + 0 . 01 )

=64×10−8= 64 \times {10}^{- 8}

x+0.01≅0.01Mx + 0 . 01 ≅ 0 . 01M

So, x(0.01)=64×10−8x ( 0 . 01 ) = 64 \times {10}^{- 8}

x=64×10−6Mx = 64 \times {10}^{- 6}M

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