JEE Main 201910 AprilMorning Shift
- Exam
- JEE Main
- Year
- 2019
- Date
- 10 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Ionic Equilibrium
JEE Main 2019 · 10 April · Morning Shift · Chemistry · Ionic Equilibrium
Consider the following statements ( a ) The pH of a mixture...
Consider the following statements
The pH of a mixture containing of and of will be approximately
Ionic product of water is temperature dependent.
A monobasic acid with has a . The degree of dissociation of this acid is .
The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are:
The pH of a mixture containing of and of will be approximately
Ionic product of water is temperature dependent.
A monobasic acid with has a . The degree of dissociation of this acid is .
The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are:
Options
- A and
- B and
- C and
- D and
Correct answer
D. and
Step-by-step solution
Strong acid + Strong base mixture
So will be more
\left[{H}^{+}\right] = \dfrac{2 \times 0.1 \times 400 - 0.1 \times 400}{800} = 0.05pH = - log {H}^{+} = - \log 0.05 = 1.3HCOOH ⇌ {H}^{+} + HCO{O}^{-}{\text{k}}_{a} = \dfrac{C{\alpha}^{2}}{\left(1 - \alpha\right)}{\text{k}}_{a} = \dfrac{C\alpha . \alpha}{\left(1 - \alpha\right)}{\text{k}}_{a} = \dfrac{\left({H}^{+}\right)\alpha}{1 - \alpha}{10}^{- 5} = {10}^{- 5} \times \dfrac{\alpha}{1 - \alpha}1 - \alpha = \alpha\alpha = \dfrac{1}{2} = 0.5
(d) Le-Chatelier’s Principle in applicable on Common Ion Effect
So will be more
\left[{H}^{+}\right] = \dfrac{2 \times 0.1 \times 400 - 0.1 \times 400}{800} = 0.05pH = - log {H}^{+} = - \log 0.05 = 1.3HCOOH ⇌ {H}^{+} + HCO{O}^{-}{\text{k}}_{a} = \dfrac{C{\alpha}^{2}}{\left(1 - \alpha\right)}{\text{k}}_{a} = \dfrac{C\alpha . \alpha}{\left(1 - \alpha\right)}{\text{k}}_{a} = \dfrac{\left({H}^{+}\right)\alpha}{1 - \alpha}{10}^{- 5} = {10}^{- 5} \times \dfrac{\alpha}{1 - \alpha}1 - \alpha = \alpha\alpha = \dfrac{1}{2} = 0.5
(d) Le-Chatelier’s Principle in applicable on Common Ion Effect