Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 201910 AprilMorning Shift
Exam
JEE Main
Year
2019
Date
10 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2019 · 10 April · Morning Shift · Chemistry · Ionic Equilibrium

Consider the following statements ( a ) The pH of a mixture...

Consider the following statements
(a)( a ) The pH of a mixture containing 400mL400mL of 0.1MH2SO40.1M{H}_{2}S{O}_{4} and 400mL400mL of 0.1MNaOH0.1MNaOH will be approximately 1.3.1.3 .
(b)( b ) Ionic product of water is temperature dependent.
(c)( c ) A monobasic acid with Ka=10−5{K}_{a} = {10}^{- 5} has a pH=5pH = 5 . The degree of dissociation of this acid is 5050% .
(d)( d ) The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are:

Options

  1. A(b)( b ) and (c)( c )
  2. B(a),(b)( a ) , ( b ) and (d)( d )
  3. C(a)( a ) and (b)( b )
  4. D(a),(b)( a ) , ( b ) and (c)( c )

Correct answer

D. (a),(b)( a ) , ( b ) and (c)( c )

Step-by-step solution

Strong acid + Strong base mixture
n[H2SO4]>n[NaOH]n\left[{H}_{2}S{O}_{4}\right] > n [ NaOH ] So H+{H}^{+} will be more
\left[{H}^{+}\right] = \dfrac{2 \times 0.1 \times 400 - 0.1 \times 400}{800} = 0.05<br/><br/>pH = - log {H}^{+} = - \log 0.05 = 1.3<br/>(b)Theionicproductofwateristemperaturedependent<br/>(c)<br/>(b) The ionic product of water is temperature dependent <br/>(c)HCOOH ⇌ {H}^{+} + HCO{O}^{-}(weakacid)<br/>(weak acid) <br/>{\text{k}}_{a} = \dfrac{C{\alpha}^{2}}{\left(1 - \alpha\right)}<br/><br/>{\text{k}}_{a} = \dfrac{C\alpha . \alpha}{\left(1 - \alpha\right)}<br/><br/>{\text{k}}_{a} = \dfrac{\left({H}^{+}\right)\alpha}{1 - \alpha}<br/><br/>{10}^{- 5} = {10}^{- 5} \times \dfrac{\alpha}{1 - \alpha}<br/><br/>1 - \alpha = \alpha<br/><br/>\alpha = \dfrac{1}{2} = 0.5
(d) Le-Chatelier’s Principle in applicable on Common Ion Effect
Practice Ionic Equilibrium on Quantrex Academy →

More from Ionic Equilibrium

Given is a concentrated solution of a weak electrolyte A_xB_y of concentration 'c' and… JEE Main 2026M_3 A_2 is a sparingly soluble salt of molar mass y g mol ^ -1 and solubility x g L ^ -1… JEE Main 2026Arrange the following resultant mixtures in increasing order of their pH values A. 10 mL… JEE Main 202620 mL of a solution of acetic acid required 28.4 mL of 0.1 M NaOH for its neutralization.… JEE Main 2026The pH of a solution obtained by mixing 5 mL of 0.1 M NH_4OH solution with 250 mL of 0.1… JEE Main 2026The first and second ionization constants of a weak dibasic acid H_2 A are 8.1 × 10^ -8… JEE Main 2026At 25°C , 20.0 mL of 0.2 M weak monoprotic acid HX is titrated against 0.2 M NaOH. The pH… JEE Main 2026The solubility product constants of Ag_2CrO_4 and AgBr are 32x and 4y respectively at 298… JEE Main 2026 Full Ionic Equilibrium list All JEE Main PYQs