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JEE Main 20139 AprilOnline
Exam
JEE Main
Year
2013
Date
9 April
Mode
Online
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2013 · 9 April · Online · Chemistry · Ionic Equilibrium

Solid Ba (NO_3)_2 is gradually dissolved in a 1.0 × 10^ -4 ~M ~Na_2...

Solid Ba\mathrm{Ba}\left(\mathrm{NO}_3\right)_2isgraduallydissolvedinais gradually dissolved in a1.0 \times 10^{-4} \mathrm{~M} \mathrm{~Na}_2 \mathrm{CO}_3solution.Atwhichconcentrationofsolution. At which concentration of\mathrm{Ba}^{2+},precipitateof, precipitate of\mathrm{BaCO}_3beginstoform?(Kspbegins to form ? \left(K_{s p}\right. for \left.\mathrm{BaCO}_3=5.1 \times 10^{-9}\right)

Options

  1. A5.1×10−5M5.1 \times 10^{-5} \mathrm{M}
  2. B7.1×10−8M7.1 \times 10^{-8} \mathrm{M}
  3. C4.1×10−5M4.1 \times 10^{-5} \mathrm{M}
  4. D8.1×10−7M8.1 \times 10^{-7} \mathrm{M}

Correct answer

A. 5.1×10−5M5.1 \times 10^{-5} \mathrm{M}

Step-by-step solution

Given Na2CO3=1.0×10−4M\mathrm{Na}_2 \mathrm{CO}_3=1.0 \times 10^{-4} \mathrm{M}∴[CO3−−]=1.0×10−4M i.e. s=1.0×10−4M\begin{aligned} & \therefore \quad\left[\mathrm{CO}_3^{--}\right]=1.0 \times 10^{-4} \mathrm{M} \\ & \text{ i.e. } \quad \mathrm{s}=1.0 \times 10^{-4} \mathrm{M} \end{aligned}AtequilibriumAt equilibrium\begin{aligned} & {\left[\mathrm{Ba}^{++}\right]\left[\mathrm{CO}_3{ }^{--}\right]=\mathrm{K}_{\mathrm{sp}} \text{\text{ of } } \mathrm{BaCO}_3} \\ & {\left[\mathrm{Ba}^{++}\right]=\frac{\mathrm{K}_{\mathrm{sp}}}{\left[\mathrm{CO}_3{ }^{--}\right]}=\frac{5.1 \times 10^{-9}}{1.0 \times 10^{-4}}} \end{aligned}$=5.1×10−5M=5.1 \times 10^{-5} \mathrm{M}
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