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JEE Advanced
Exam
JEE Advanced
Subject
Chemistry
Chapter
General Principles and Processes of Isolation of Metals

JEE Advanced · Chemistry · General Principles and Processes of Isolation of Metals

Consider the following metallurgical processes. (i) Heating impure...

Consider the following metallurgical processes. (i) Heating impure metal with CO and distilling the resulting volatile carbonyl (b.p. 43∘C43^{{}^{{}^{\circ}}} \mathrm{C} ) and finally decomposition at 150∘−200∘C150^{{}^{{}^{\circ}}}-200^{{}^{{}^{\circ}}} \mathrm{C} to get the pure metal (ii) Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence of air to let the oxide react with unchanged metal sulphide (iii) Electrolysis of the molten electrolyte containing approximately equal amounts of the metal chloride and NaCl to obtained the metal "The processes used for obtaining magnesium, nickel and copper are respectively :

Options

  1. A(i), (ii) and (iii)
  2. B(ii), (iii) and (i)
  3. C(iii), (i) and (ii)
  4. D(ii), (i) and (iii)

Correct answer

C. (iii), (i) and (ii)

Step-by-step solution

(i) Ni (impure) +4CO→50∘C[Ni(CO4)] (volatile) →230∘CNi (pure) +4CO↑\underset{\text { (impure) }}{\mathrm{Ni}}+4 \mathrm{CO} \xrightarrow{50^{{}^{{}^{\circ}}} \mathrm{C}} \underset{\text { (volatile) }}{\left[\mathrm{Ni}\left(\mathrm{CO}_4\right)\right]} \xrightarrow{230^{{}^{{}^{\circ}}} \mathrm{C}} \underset{\text { (pure) }}{\mathrm{Ni}}+4 \mathrm{CO} \uparrow (ii) Cu2 S+32O2→ΔCu2O+SO2Cu2 S+2Cu2O→ high  high 6Cu+SO2\begin{aligned} & \text { (ii) } \mathrm{Cu}_2 \mathrm{~S}+\frac{3}{2} \mathrm{O}_2 \xrightarrow{\Delta} \mathrm{Cu}_2 \mathrm{O}+\mathrm{SO}_2 \\ & \mathrm{Cu}_2 \mathrm{~S}+2 \mathrm{Cu}_2 \mathrm{O} \xrightarrow[\text { high }]{\text { high }} 6 \mathrm{Cu}+\mathrm{SO}_2\end{aligned}$(iii)(iii)\mathrm{MgCl}(\mathrm{s}) \xrightarrow{\text { electrolysis }} \mathrm{Mg}^{2+}(1)+2 \mathrm{Cl}(l)Atcathode:(l) At cathode :\mathrm{Mg}^{2+}+2 \mathrme^{-} \longrightarrow \mathrm{Mg}(\mathrm{s})Atanode:At anode :2 \mathrm{Cl}^{-}(\mathrm{l}) \longrightarrow \mathrm{Cl}_2(\mathrm{~g})+2 \mathrme^{-}$
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