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JEE Main 202624 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
24 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2026 · 24 January · Morning Shift · Chemistry · Redox Reactions

X and Y are the number of electrons involved, respectively during...

X and Y are the number of electrons involved, respectively during the oxidation of I−\mathrm{I}^{-}to I2\mathrm{I}_{2} and S2−\mathrm{S}^{2-} to S by acidified K2Cr2O7\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}. The value of X+Y\mathrm{X}+\mathrm{Y} is ____\_\_\_\_.

Correct answer

0

Step-by-step solution

In acidic medium, K2Cr2O7K_2Cr_2O_7 acts as a strong oxidizing agent where Cr2O72−Cr_2O_7^{2-} is reduced to Cr3+Cr^{3+}.
The reduction half-reaction is: Cr2O72−+14H++6e−→2Cr3++7H2OCr_2O_7^{2-} + 14H^+ + 6e^- \rightarrow 2Cr^{3+} + 7H_2O.
For the oxidation of I−I^- to I2I_2:
The balanced oxidation half-reaction is 2I−→I2+2e−2I^- \rightarrow I_2 + 2e^-.
To balance the electrons with the reduction half-reaction (6 electrons), we multiply the oxidation half-reaction by 3:
6I−→3I2+6e−6I^- \rightarrow 3I_2 + 6e^-.
Thus, the number of electrons involved in the balanced redox reaction for I−I^- oxidation is X=6X = 6.
For the oxidation of S2−S^{2-} to SS:
The balanced oxidation half-reaction is S2−→S+2e−S^{2-} \rightarrow S + 2e^-.
To balance the electrons with the reduction half-reaction (6 electrons), we multiply the oxidation half-reaction by 3:
3S2−→3S+6e−3S^{2-} \rightarrow 3S + 6e^-.
Thus, the number of electrons involved in the balanced redox reaction for S2−S^{2-} oxidation is Y=6Y = 6.
The value of X+Y=6+6=12X + Y = 6 + 6 = 12.
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