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The correct sequence of reagents which would convert p-Nitrotoluene to p-Iodobenzoic acid is

Options

  1. A(i) Br ₂+ FeBr ₂ , (ii) Mg in ether, then CO ₂ , (iii) 3 H ₂ and Pt or Ni catalyst, (iv) HNO ₂, 0^ C , (v) KI
  2. B(i) Br ₂ in CCl ₄ and heat, (ii) NaI in acetone, (iii) 3 H ₂ and Pt or Ni catalyst, (iv) HNO ₂, 0^ C ,( v ) H
  3. C(i) 3 H ₂ and Pt or Ni catalyst, (ii) HNO ₂, 0^ C , (iii) Cu ₂ Br ₂+ HBr , (iv) KMnO ₄ and heat, (v) KI soluti
  4. D(i) KMnO ₄ and heat, (ii) 3 H ₂ and Pt or Ni catalyst, (iii) HNO ₂, 0^ C , (iv) KI solution

Correct answer

D. (i) KMnO ₄ and heat, (ii) 3 H ₂ and Pt or Ni catalyst, (iii) HNO ₂, 0^ C , (iv) KI solution

Step-by-step solution

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