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JEE Main & Advanced NSEC PYQs with solutions

Chapter-wise NSEC previous year questions for JEE Main & Advanced. Open any question for options, correct answer and solution.

606 questions30 chapters
1

At constant volume, 6.0 mol of H ₂ gas at 0^ C and 100 kPa was heated to 250 kPa . The molar heat of H ₂ at constant pressure ( C _ P )=28.9 ~J ~mol ⁻¹ . ( assume that the heat cap

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2

Hydrazine used in rocket fuels can be obtained by the reaction of ammonia and hydrogen peroxide according to the following equation 2 NH ₃( ~g )+ H ₂ O ₂( l ) N ₂ H ₄( l )+2 H ₂ O

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3

The daily energy requirement of a teenager is 7800 kJ . As calculated from the data given in the table below, the amount of glucose he has to consume (g) per day assuming that the

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4

If the radius of the hydrogen atom is 53 pm , the radius of the He ⁺ ion is close to

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5

An electron present in the third excited state of a H atom returns to the first excited state and then to the ground state. If ₁ and ₂ are the wavelengths of light emitted in these

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6

The ratio of the energy of the electron in ground state of hydrogen atom to that of the electron in the first excited state of Be ³⁺ is

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7

The crystal defect indicated in the diagram below is

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8

The cubic unit cell of an oxide of metals A and B is as given below, in which oxygen, A and B are represented by open circles, crossed circles and dark circles respectively. The fo

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9

Read carefully all the three statements on defects in solids: (i) In Frenkel defect, interstitial Ag ⁺ site is surrounded tetrahedrally by four Cl ⁻ ions and four Ag ⁺ ions, where

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10

When 100 g each of the salts NaCl , MgSO ₄, Ca ( NO ₃ )₂, ~K ₂ CO ₃ , were dissolved separately in 1.0 kg of water, the solution with the highest boiling point will be of

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11

About sea water, which of the following statement/s is/are correct? I. Frozen sea water melts at a lower temperature than pure ice II. Boiling point of sea water increases as it ev

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12

A student intended to prepare 1000 mL of a 10 ppm solution of K ⁺ from KCl . He made appropriate calculations, weighed the salt accordingly and prepared the solution. However, afte

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13

NaOH solution is added dropwise to HCl solution and the conductance of the mixture is measured after addition of each drop. The variation of conductance with volume of NaOH added i

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14

Reaction E ₀ / V Ag Ag ⁺+ e ⁻ -0.80 Cr ³⁺+3 e ⁻ 3 Cr -0.74 Zn ²⁺+2 e ⁻ Zn -0.76 I ₂( ~s )+2 e ⁻ 2 I ⁻ 0.54 Co ²⁺+2 e ⁻ Co -0.28 Ni ²⁺+2 e ⁻ Ni -0.26 The best reducing agent among t

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15

When a medal is electroplated with silver (Ag)

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16

When excess KMnO ₄ is added to concentrated H ₂ SO ₄ , an oily green colored covalent compound Y is formed. Which of the following statements is/ are true for the above reaction.

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17

Which of the following statements is not true for Ce ³⁺ and Yb ³⁺ ?

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18

An excess of aqueous ammonia is added to three different flasks ( F₁, F₂, F₃ ) containing aqueous solutions of CuSO ₄, Fe ₂ ( SO ₄ )₃ and NiSO ₄ respectively. Which of the followin

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19

For an elementary rearrangement reaction A P , the following data were recorded at 303 K , when [ P ]₀=0 : Set No. [ A ]₀ / mol L ⁻¹ Rate of conversion of A / mol L ⁻¹ ⁻¹ 1 0.340 0

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20

The kinetic data recorded at 278 K for the reaction NH ₄ ⁺(a q)+ NO ₂ ⁻(a q) N ₂(g)+2 H ₂ O (I) is Set No. [ NH ₄⁺ ] / M [ NO ₂⁻ ] / M Rate of reaction/ M s-1 1 0.24 0.10 7.2 10⁻⁶

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21

The reaction X + Y Z is first order with respect to X and second order with respect to Y . The initial rate of formation of Z = R mol ⁻ dm ^3 sec ⁻¹ when [ X ]₀ and [ Y ]₀ are 0.40

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22

A colorless water-soluble compound on strong heating liberates a brown colored gas and leaves a yellow residue that turns white on cooling. An aqueous solution of the original soli

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23

Addition of dil. HCl to an aqueous solution of a mixture of two inorganic salts yielded white precipitate E and filtrate F . Precipitate E dissolved in hot water. F in alkaline ali

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24

Passing H ₂ ~S gas into a mixture of Mn ²⁺, Ni ²⁺, Cu ²⁺ and Hg ²⁺ in an acidified aqueous solution precipitates

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25

Among the following, number of oxygen atoms present is the maximum in

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26

Which of the following mixtures of water and H ₂ SO ₄ would have mass percentage of H ₂ SO ₄ close to 30 ?

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27

A 500 mL glass flask is filled at 298 K and 1 atm . pressure with three diatomic gases X, Y and Z . The initial volume ratio of the gases before mixing was 5: 3: 1 . The density of

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28

In ammonia the bond angle is 107^ 48^ while in SbH ₃ the bond angle is about 91^ 18^ . The correct explanation among the followings is/ are

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29

Which of the following compounds contain 3-centered 2-electron bonding? (i) [ BeF ₂ ]_ n (ii) [ Be ( CH ₃ )₃ ]_ n (iii) [ BeCl ₂ ]_ n (iv) [ BeH ₂ ]_ n

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30

In the Lewis structure of ozone ( O ₃ ) , the formal charge on the central oxygen atom is

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31

How many isomers are possible for complex [ Co ( ox )₂ Cl ₂ ]⁺ ?

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32

Which one of the following reactions is correct?

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33

Which of the following statements about ammonium cerium(IV) nitrate, ( NH ₄ )₂ [ Ce ( NO ₃ )₆ ] is false?

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34

Equal masses of ethane and hydrogen gas are present in a container at 25^ C . The fraction of the total pressure exerted by ethane gas is

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35

The van der Waals equation for one mole of a real gas can be written as ( P + a / V ^2 )( V - b )= RT . For the gases H ₂, NH ₃ , and CH ₄ , the value of ' a ' ( . bar L ⁻² mol ⁻²

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36

Which of the following will not give a straight line plot for an ideal gas?

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37

The pH of a 1.0 10⁻³ ~mol ~L ⁻¹ solution of a weak acid HA is 3.60 . The dissociation constant of the acid is

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38

The solution with pH value close to 1 is

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39

The colour changes of an indicator HIn in acid base titrations is given below Which of the following statements is correct?

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40

Match the compounds given in list I with their characteristic reactions in list II List-I (Compound) List-II (Reaction) 1 Tertbutyl amine a Liberation of ammonia on heating with aq

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