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JEE Main & Advanced NSEC PYQs with solutions

Chapter-wise NSEC previous year questions for JEE Main & Advanced: 606 questions in 30 chapters. Largest chapters: Some Basic Concepts of Chemistry (60), Electrochemistry (52) and Thermodynamics (C) (50). Open any question for options, correct answer and solution.

606 questions30 chapters

JEE NSEC chapters

Sample NSEC questions

1

At constant volume, 6.0 mol of H_2 gas at 0^ ^ ^ ∘ C and 100 kPa was heated to 250 kPa . The molar heat of H_2 at constant pressure (C_ P )=28.9 ~J ~mol^ -1 . ( assume that the

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2

Hydrazine used in rocket fuels can be obtained by the reaction of ammonia and hydrogen peroxide according to the following equation 2 NH_3(~g)+H_2 O_2(l) arrow N_2 H_4(l)+2 H_2

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3

The daily energy requirement of a teenager is 7800 kJ . As calculated from the data given in the table below, the amount of glucose he has to consume (g) per day assuming that the

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4

If the radius of the hydrogen atom is 53 pm , the radius of the He^ + ion is close to

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5

An electron present in the third excited state of a H atom returns to the first excited state and then to the ground state. If λ_1 and λ_2 are the wavelengths of light emitted in

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6

The ratio of the energy of the electron in ground state of hydrogen atom to that of the electron in the first excited state of Be^ 3+ is

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7

The crystal defect indicated in the diagram below is

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8

The cubic unit cell of an oxide of metals A and B is as given below, in which oxygen, A and B are represented by open circles, crossed circles and dark circles respectively. The

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9

Read carefully all the three statements on defects in solids: (i) In Frenkel defect, interstitial Ag^ + site is surrounded tetrahedrally by four Cl^ - ions and four Ag^ + ions

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10

When 100 g each of the salts NaCl, MgSO_4, Ca(NO_3)_2, ~K_2 CO_3 , were dissolved separately in 1.0 kg of water, the solution with the highest boiling point will be of

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11

About sea water, which of the following statement/s is/are correct? I. Frozen sea water melts at a lower temperature than pure ice II. Boiling point of sea water increases as it

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12

A student intended to prepare 1000 mL of a 10 ppm solution of K^ + from KCl . He made appropriate calculations, weighed the salt accordingly and prepared the solution. However

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13

NaOH solution is added dropwise to HCl solution and the conductance of the mixture is measured after addition of each drop. The variation of conductance with volume of NaOH added

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14

Reaction E_0 / V Agarrow Ag^ + + ^ - -0.80 Cr^ 3+ +3 ^ - arrow 3 Cr -0.74 Zn^ 2+ +2 ^ - arrow Zn -0.76 I_2(~s)+2 ^ - arrow 2 I^ - 0.54 Co^ 2+ +2 ^ - arrow Co -0.28 Ni^ 2+ +2 ^

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15

When a medal is electroplated with silver (Ag)

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16

When excess KMnO_4 is added to concentrated H_2 SO_4 , an oily green colored covalent compound Y is formed. Which of the following statements is/ are true for the above reaction.

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17

Which of the following statements is not true for Ce^ 3+ and Yb^ 3+ ?

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18

An excess of aqueous ammonia is added to three different flasks ( F_1, F_2, F_3 ) containing aqueous solutions of CuSO_4, Fe_2(SO_4)_3 and NiSO_4 respectively. Which of the

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19

For an elementary rearrangement reaction A leftharpoons P , the following data were recorded at 303 K , when [P]_0=0 : Set No. [A]_0 / molL^ -1 Rate of conversion of A/ molL^ -1 ^

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20

The kinetic data recorded at 278 K for the reaction NH_4 ^ + (a q)+NO_2 ^ - (a q) arrow N_2(g)+2 H_2 O(I) is Set No. [NH_4^ + ] / M [NO_2^ - ] / M Rate of reaction/ M s-1 1 0.24

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21

The reaction X+Y arrow Z is first order with respect to X and second order with respect to Y . The initial rate of formation of Z=R mol^ - dm^3 ^ -1 when [X]_0 and [Y]_0 are 0.40

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22

A colorless water-soluble compound on strong heating liberates a brown colored gas and leaves a yellow residue that turns white on cooling. An aqueous solution of the original

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23

Addition of dil. HCl to an aqueous solution of a mixture of two inorganic salts yielded white precipitate E and filtrate F . Precipitate E dissolved in hot water. F in alkaline

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24

Passing H_2~S gas into a mixture of Mn^ 2+ , Ni^ 2+ , Cu^ 2+ and Hg^ 2+ in an acidified aqueous solution precipitates

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25

Among the following, number of oxygen atoms present is the maximum in

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26

Which of the following mixtures of water and H_2 SO_4 would have mass percentage of H_2 SO_4 close to 30 ?

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27

A 500 mL glass flask is filled at 298 K and 1 atm . pressure with three diatomic gases X, Y and Z . The initial volume ratio of the gases before mixing was 5: 3: 1 . The density

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28

In ammonia the bond angle is 107^ ^ ^ ∘ 48^ while in SbH_3 the bond angle is about 91^ ^ ^ ∘ 18^ . The correct explanation among the followings is/ are

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29

Which of the following compounds contain 3-centered 2-electron bonding? (i) [BeF_2]_ n (ii) [Be(CH_3)_3]_ n (iii) [BeCl_2]_ n (iv) [BeH_2]_ n

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30

In the Lewis structure of ozone (O_3) , the formal charge on the central oxygen atom is

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31

How many isomers are possible for complex [Co(ox)_2 Cl_2]^ + ?

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32

Which one of the following reactions is correct?

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33

Which of the following statements about ammonium cerium(IV) nitrate, (NH_4)_2 [Ce(NO_3)_6] is false?

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34

Equal masses of ethane and hydrogen gas are present in a container at 25^ ^ ^ ∘ C . The fraction of the total pressure exerted by ethane gas is

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35

The van der Waals equation for one mole of a real gas can be written as (P+a / V^2)(V-b)=RT . For the gases H_2, NH_3 , and CH_4 , the value of ' a ' (. bar L^ -2 mol^ -2 ) are

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36

Which of the following will not give a straight line plot for an ideal gas?

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37

The pH of a 1.0 × 10^ -3 ~mol ~L^ -1 solution of a weak acid HA is 3.60 . The dissociation constant of the acid is

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38

The solution with pH value close to 1 is

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39

The colour changes of an indicator HIn in acid base titrations is given below Which of the following statements is correct?

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40

Match the compounds given in list I with their characteristic reactions in list II List-I (Compound) List-II (Reaction) 1 Tertbutyl amine a Liberation of ammonia on heating with

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