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Olympiad workbookNSECCoordination Compounds

Cyanide ion is a very good complexing agent and also functions as a reducing agent. Hence many cyanide complexes of metals are known. Addition of an aqueous solution of KCN to a solution of copper sulphate yields a white precipitate which is soluble in excess of aqueous KCN to form the complex:

Options

  1. A[ Cu ( CN )₄ ]¹⁻
  2. B[ Cu ( CN )₄ ]²⁻
  3. C[ Cu ( CN )₄ ]³⁻
  4. D[ Cu ( CN )₄ ]⁴⁻

Correct answer

C. [ Cu ( CN )₄ ]³⁻

Step-by-step solution

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