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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Electrochemistry

Olympiad workbook · NSEC · Electrochemistry

The standard electrode potential (E^0) of the Daniel cell is 1.1 V...

The standard electrode potential (E0)\left(\mathrm{E}^0\right) of the Daniel cell is 1.1 V and the overall cell reaction can be represented as Zn(s)+Cu2+(aq)→Zn2+(aq)+Cu(s)\mathrm{Zn}(\mathrm{s})+\mathrm{Cu}^{2+}(\mathrm{aq}) \rightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{Cu}(\mathrm{s}). Under which of the following conditions will the cell potential be higher than 1.1 V ?

Options

  1. A1.0MZn2+,1.0MCu2+1.0 \mathrm{M} \mathrm{Zn}^{2+}, 1.0 \mathrm{M} \mathrm{Cu}^{2+}
  2. B1.2MZn2+,1.2MCu2+1.2 \mathrm{M} \mathrm{Zn}^{2+}, 1.2 \mathrm{M} \mathrm{Cu}^{2+}
  3. C0.1MZn2+,1.0MCu2+0.1 \mathrm{M} \mathrm{Zn}^{2+}, 1.0 \mathrm{M} \mathrm{Cu}^{2+}
  4. D1.0MZn2+,0.01MCu2+1.0 \mathrm{M} \mathrm{Zn}^{2+}, 0.01 \mathrm{M} \mathrm{Cu}^{2+}

Correct answer

C. 0.1MZn2+,1.0MCu2+0.1 \mathrm{M} \mathrm{Zn}^{2+}, 1.0 \mathrm{M} \mathrm{Cu}^{2+}

Step-by-step solution

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