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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Haloalkanes and Haloarenes

Olympiad workbook · NSEC · Haloalkanes and Haloarenes

A group which departs from the substrate in a nucleophilic...

A group which departs from the substrate in a nucleophilic substitution reaction is called a leaving group. The ease of departure is determined by the acidity of the conjugate acid of the leaving group; higher the acidity better is the leaving group. The correct order of the reactivity of the following compounds in a given nucleophilic reaction is-

Options

  1. AR−Cl>R−OCOCH3>R−OSO2CH3>RI\mathrm{R}-\mathrm{Cl}>\mathrm{R}-\mathrm{OCOCH}_3>\mathrm{R}-\mathrm{OSO}_2 \mathrm{CH}_3>\mathrm{RI}
  2. BR−OSO2CH3>R−Cl>R−OCOCH3>ROH\mathrm{R}-\mathrm{OSO}_2 \mathrm{CH}_3>\mathrm{R}-\mathrm{Cl}>\mathrm{R}-\mathrm{OCOCH}_3>\mathrm{ROH}
  3. CR−\mathrm{R}-\mathrm{I}>RNH2>R−OCOCH3>R−OSO2CH3>\mathrm{RNH}_2>\mathrm{R}-\mathrm{OCOCH}_3>\mathrm{R}-\mathrm{OSO}_2 \mathrm{CH}_3
  4. DR−Br>R−OSO2CH3>R−OCOCH3>ROCH3\mathrm{R}-\mathrm{Br}>\mathrm{R}-\mathrm{OSO}_2 \mathrm{CH}_3>\mathrm{R}-\mathrm{OCOCH}_3>\mathrm{ROCH}_3

Correct answer

D. R−Br>R−OSO2CH3>R−OCOCH3>ROCH3\mathrm{R}-\mathrm{Br}>\mathrm{R}-\mathrm{OSO}_2 \mathrm{CH}_3>\mathrm{R}-\mathrm{OCOCH}_3>\mathrm{ROCH}_3

Step-by-step solution

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