The solution with pH value close to 1 is

Options

1. A10 mL of $0.1 \mathrm{M} \mathrm{HCl}+90 \mathrm{~mL}$ of 0.1 M NaOH
2. B55 mL of $0.1 \mathrm{M} \mathrm{HCl}+45 \mathrm{~mL}$ of 0.1 M NaOH
3. C75 mL of $0.2 \mathrm{M} \mathrm{HCl}+25 \mathrm{~mL}$ of 0.2 M NaOH
4. D75 mL of $0.2 \mathrm{M} \mathrm{HCl}+25 \mathrm{~mL}$ of 0.1 M NaOH