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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
States of Matter

Olympiad workbook · NSEC · States of Matter

The van der Waals equation for one mole of a real gas can be...

The van der Waals equation for one mole of a real gas can be written as \left(\mathrm{P}+\mathrm{a} / \mathrm{V}^2\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}.Forthegases. For the gases\mathrm{H}_2, \mathrm{NH}_3,and, and\mathrm{CH}_4,thevalueof′a′(, the value of ' a ' \left(\right. bar L−2mol−2\mathrm{L}^{-2} \mathrm{mol}^{-2} ) are 0.2453,4.1700.2453,4.170 and 2.253 respectively. Which of the following can be inferred from the 'a' values?

Options

  1. ANH3\mathrm{NH}_3 can be most easily liquefied
  2. BH2\mathrm{H}_2 can be most easily liquified
  3. Cvalue of 'a' for CH4\mathrm{CH}_4 is less than that of NH3\mathrm{NH}_3 because it has the lower molar mass
  4. Dintermolecular forces are the strongest in hydrogen

Correct answer

A. NH3\mathrm{NH}_3 can be most easily liquefied

Step-by-step solution

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