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JEE Main 20238 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
8 April
Shift
Morning Shift
Subject
Chemistry
Chapter
s Block Elements

JEE Main 2023 · 8 April · Morning Shift · Chemistry · s Block Elements

Given below are two statements : Statement I : Lithium and...

Given below are two statements :

Statement I : Lithium and Magnesium do not form superoxide

Statement II : The ionic radius of Li+{Li}^{+} is larger than ionic radius of Mg2+{Mg}^{2 +} In the light of the above statements, choose the most appropriate answer from the questions given below :

In the light of the above statements, choose the most appropriate answer from the questions given below :

Options

  1. AStatement I is incorrect but Statement II is correct
  2. BStatement I is correct but Statement II is incorrect
  3. CBoth statement I and Statement II are incorrect
  4. DBoth Statement I and Statement II are correct

Correct answer

D. Both Statement I and Statement II are correct

Step-by-step solution

The values of ionic radii of Li+=0.74A˚{Li}^{+} = 0 . 74Åand Mg+2=0.72A˚{Mg}^{+ 2} = 0 . 72Å respectively. Thus, the lithium ion with +1+ 1 charge is only marginally larger than the magnesium ion having a charge of +2+ 2.

The superoxide releases the most energy when formed, the superoxide is preferentially formed for the larger metals where the more complex anions are not polarised. So, LiandMgLiandMg do not form superoxides.

Therefore both the given options were correct.

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