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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Surface Chemistry

JEE Main 2023 · 31 January · Evening Shift · Chemistry · Surface Chemistry

Match List I with List II List I List II A Physisorption I Single...

Match List I with List II

List I List II
A Physisorption I Single Layer Adsorption
B Chemisorption II 20−40kJmol−120 - 40kJ{mol}^{- 1}
C N2(g)+3H2(g)⟶Fe(s)2NH3(g){N}_{2}\left(g\right) + 3{H}_{2}\left(g\right)\overset{Fe ( s )}{⟶}2{NH}_{3}\left(g\right) III Chromatography
D Analytical Application or Adsorption IV Heterogeneous catalysis

Choose the correct answer from the options given below:

Options

  1. AA-III, B-IV, C-I, D-II
  2. BA-II, B-III, C-I, D-IV
  3. CA-II, B-I, C-IV, D-III
  4. DA-IV, B-II, C-III, D-I

Correct answer

C. A-II, B-I, C-IV, D-III

Step-by-step solution

(A) In physisorption, the enthalpy heat is low and lies between 20−40kJmol−120 - 40kJ{mol}^{- 1}. In physisorption, multilayers of adsorbed particles are formed.

(B) In chemisorption, the enthalpy heat is high and lies within the range of 40−200kJmol−140 - 200kJ{mol}^{- 1}. In chemisorption, a monolayer of adsorbed particles is formed.

(C) N2(g)+3H2(g)⟶Fe(s)2NH3(g){N}_{2}\left(g\right) + 3{H}_{2}\left(g\right)\overset{Fe ( s )}{⟶}2{NH}_{3}\left(g\right)

Heterogeneous catalysts occupy a different phase. Generally, heterogeneous catalysts are solid compounds that are added to liquid or gas reaction mixtures. Fe is used as a heterogeneous catalyst in the Haber process.

(D) In the process of adsorption chromatography, different compounds are adsorbed on the adsorbent to different degrees based on the absorptivity of the component.

So, the correct matching is A-IV, B-II, C-III, D-I.

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