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JEE Main 202229 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Surface Chemistry

JEE Main 2022 · 29 July · Evening Shift · Chemistry · Surface Chemistry

Given below are the critical temperatures of some of the gases: Gas...

Given below are the critical temperatures of some of the gases:

Gas Critical temperature (K)\left(K\right)
HeHe 5.25 . 2
CH4{CH}_{4} 190190
CO2{CO}_{2} 304.2304 . 2
NH3{NH}_{3} 405.5405 . 5

The gas showing least adsorption on a definite amount of charcoal is

Options

  1. AHeHe
  2. BCH4{CH}_{4}
  3. CCO2{CO}_{2}
  4. DNH3{NH}_{3}

Correct answer

A. HeHe

Step-by-step solution

The amount of gas adsorbed by a solid depends on the nature of gas. In general, easily liquefiable gases (i.e., with higher critical temperatures) are readily adsorbed as van der Waals’ forces are stronger near the critical temperatures. Thus, 1g of activated charcoal adsorbs more sulphur dioxide (critical temperature 630K), than methane (critical temperature 190K) which is still more than 4.5 mL of dihydrogen (critical temperature 33K).

So, more the critical temperature of gas greater is the ease of liquefaction hence greater is the adsorption.

Hence, among the given gases ammonia is adsorbed most and helium the least on definite amount of charcoal.

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