JEE Main202229 Jul 2022Evening ShiftChemistrySurface ChemistryActual
Given below are the critical temperatures of some of the gases: Gas Critical temperature K He 5 . 2 CH 4 190 CO 2 304 . 2 NH 3 405 . 5 The gas showing least adsorption on a definite amount of charcoal is
Options
- AHe
- BCH 4
- CCO 2
- DNH 3
Correct answer
A. He
Step-by-step solution
The amount of gas adsorbed by a solid depends on the nature of gas. In general, easily liquefiable gases (i.e., with higher critical temperatures) are readily adsorbed as van der Waals’ forces are stronger near the critical temperatures. Thus, 1g of activated charcoal adsorbs more sulphur dioxide (critical temperature 630K), than methane (critical temperature 190K) which is still more than 4.5 mL of dihydrogen (critical temperature 33K). So, more the critical temperature of gas greater is the ease of liquefac