Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202131 AugustEvening Shift
Exam
JEE Main
Year
2021
Date
31 August
Shift
Evening Shift
Subject
Chemistry
Chapter
Surface Chemistry

JEE Main 2021 · 31 August · Evening Shift · Chemistry · Surface Chemistry

CH _ 4 is adsorbed on 1g charcoal at 0 ° C following the Freundlich...

CH4{CH}_{4} is adsorbed on 1g1g charcoal at 0°C0 ° C following the Freundlich adsorption isotherm. 10.0mL10 . 0mL of CH4{CH}_{4} is adsorbed at 100mm100mm of Hg,Hg, whereas 15.0mL15 . 0mL is adsorbed at 200mm200mm of Hg.Hg . The volume of CH4{CH}_{4} adsorbed at 300mm300mm of HgHg is 10xmL.{10}^{x}mL . The value of xx is _________ ×10−2.\times {10}^{- 2} . (Nearest integer)
[Use log⁡102=0.3010,log⁡103=0.4771\log_{10}2 = 0 . 3010, \log_{10}3 = 0 . 4771]

Correct answer

0

Step-by-step solution

\dfrac{x}{m} = Kp\dfrac{1}{n}</p><p></p><p>x ∝ Vforthesamegas<br/><br />\dfrac{10}{1} = K(100)1n\left(100\right)\dfrac{1}{n} ...(1)
151=K\dfrac{15}{1} = K\left(200\right)\dfrac{1}{n}....(2)<br/>....(2)<br />\dfrac{V}{1} = K(300)1n\left(300\right)\dfrac{1}{n} ...(3)
Divide (2) to (1) =1510=21n= \dfrac{15}{10} = 2\dfrac{1}{n}
log⁡(32)=1nlog⁡2\log \left(\dfrac{3}{2}\right) = \dfrac{1}{n}\log 2
1n=0.4771−0.30100.3010=0.585\dfrac{1}{n} = \dfrac{0 . 4771 - 0 . 3010}{0 . 3010} = 0 . 585
Divide (3) to (1) =V10=31n= \dfrac{V}{10} = 3\dfrac{1}{n}
log⁡(V10)=1nlog⁡3\log \left(\dfrac{V}{10}\right) = \dfrac{1}{n}\log 3
log⁡(V10)=0.585×0.4771=0.2791\log \left(\dfrac{V}{10}\right) = 0 . 585 \times 0 . 4771 = 0 . 2791
V10=100.2791\dfrac{V}{10} = {10}^{0 . 2791}
V=10×100.2791=101.2791=10xV = 10 \times {10}^{0 . 2791} = {10}^{1 . 2791} = {10}^{x}
x=1.2791=127.91×10−2≈128×10−2x = 1 . 2791 = 127 . 91 \times {10}^{- 2} \approx 128 \times {10}^{- 2}

Practice Surface Chemistry on Quantrex Academy →

More from Surface Chemistry

At a given temperature, 0.45 g of acetic acid in 50 mL of water is shaken with 1.0 g of… JEE Advanced 2026Adsorption of phenol from its aqueous solution on to fly ash obeys Freundlich isotherm.… JEE Advanced 2025Consider the following statements related to colloids. (I) Lyophobic colloids are not… JEE Advanced 202320mL of 0 . 5MNaCl is required to coagulate 200mL of As _ 2 S _ 3 solution in 2 hours.… JEE Main 2023Given below are two statements, one is labelled as Assertion A and the other is labelled… JEE Main 2023What happens when a lyophilic sol is added to a lyophobic sol? JEE Main 2023Four gases, A, B, C and D have critical temperatures 5 . 3, 33 . 2, 126 . 0 and 154 . 3K… JEE Main 2023The number of correct statements about modern adsorption theory of heterogeneous… JEE Main 2023 Full Surface Chemistry list All JEE Main PYQs