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JIPMER 2004
Exam
JIPMER
Year
2004
Subject
Chemistry
Chapter
d and f Block Elements

JIPMER 2004 · Chemistry · d and f Block Elements

Which of the following turns potassium dichromate paper green?

Which of the following turns potassium dichromate paper green?

Options

  1. ANO2\mathrm{NO}_2
  2. BHCl
  3. CNH3\mathrm{NH}_3
  4. DSO2\mathrm{SO}_2

Correct answer

D. SO2\mathrm{SO}_2

Step-by-step solution

SO2\mathrm{SO}_2 gas is a reducing agent, hence turns dichromate paper green due to formation of chromium sulphate. Sulphite radical (SO32−)\left(\mathrm{SO}_3^{2-}\right) is identified by this: K2Cr2O7+3SO2+H2SO4⟶Cr2(SO4)2 green +K2SO4+H2O\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+3 \mathrm{SO}_2+\mathrm{H}_2 \mathrm{SO}_4 \longrightarrow \underset{\text{ green }}{\mathrm{Cr}_2\left(\mathrm{SO}_4\right)_2} +\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{O}
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