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JIPMER 2014
Exam
JIPMER
Year
2014
Subject
Chemistry
Chapter
Environmental Chemistry

JIPMER 2014 · Chemistry · Environmental Chemistry

In Fischer-Ringe's method of separation of nobles gas mixture from...

In Fischer-Ringe's method of separation of nobles gas mixture from air, \qquad is used

Options

  1. A90%CaC2+10%CaCl290 \% \mathrm{CaC}_2+10 \% \mathrm{CaCl}_2
  2. Bcoconut charcol
  3. Csoda lime + potash solution
  4. D90%CaCO3+10%90 \% \mathrm{CaCO}_3+10 \% urea

Correct answer

A. 90%CaC2+10%CaCl290 \% \mathrm{CaC}_2+10 \% \mathrm{CaCl}_2

Step-by-step solution

In Fischer Ringe's method, air free from moisture and CO2\mathrm{CO}_2 is passed over a heated mixture (800∘C)\left(800^{\circ} \mathrm{C}\right) of 90%CaC2+10%CaCl290 \% \mathrm{CaC}_2+10 \% \mathrm{CaCl}_2 in an iron tube, when following reactions take place CaC2+N2→800∘CCaCN2+C\mathrm{CaC}_2+\mathrm{N}_2 \xrightarrow{800^{\circ} \mathrm{C}} \mathrm{CaCN}_2+\mathrm{C}2C+O⟶2COC+O2⟶CO2\begin{aligned} & 2 \mathrm{C}+\mathrm{O} \longrightarrow 2 \mathrm{CO} \\ & \mathrm{C}+\mathrm{O}_2 \longrightarrow \mathrm{CO}_2\end{aligned}2CaC2+3CO2⟶2CaCO3+5CCuO+CO⟶Cu+CO2\begin{array}{r}2 \mathrm{CaC}_2+3 \mathrm{CO}_2 \longrightarrow 2 \mathrm{CaCO}_3+5 \mathrm{C} \\ \mathrm{CuO}+\mathrm{CO} \longrightarrow \mathrm{Cu}+\mathrm{CO}_2\end{array}CO2\mathrm{CO}_2 gas is now absorbed by KOH solution. Thus a mixture of inert gases is obtained.
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