KCET2010ChemistryAldehydes and Ketones
One mole of an organic compound A with the formula C ₃ H ₈ O reacts completely with two moles of HI to form X and Y . When Y is boiled with aqueous alkali it forms Z. Z answers the iodoform test. The compound A is
Options
- Apropan-2-ol
- Bpropan-1-ol
- Cethoxyethane
- Dmethoxyethane
Correct answer
D. methoxyethane
Step-by-step solution
Molecular formula C ₃ H ₈ O ( C _ n H _ 2 n +2 O ) suggests that the organic compound is either alcohol or ether. Since, the compound on reaction with HI gives two different compounds, it must be an unsymmetrical ether, and its formula must be CH ₃ OC ₂ H ₅ (methoxyethane). The reactions are as follows. C ₂ H ₅ OH + (aqueous) NaOH + I ₂ iodoform CHI ₃ + HCOONa + H ₂ O + NaI