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KCET2010ChemistryCarboxylic Acid Derivatives

Chloroacetic acid is a stronger acid than acetic acid. This can be explained using

Options

  1. A- M effect
  2. B- I effect
  3. C+ M effect
  4. D+ I effect

Correct answer

B. - I effect

Step-by-step solution

-Cl is an electron withdrawing (ie, -I showing) group. It withdraws electrons when attached to the carboxylic acid and decreases the electron density on the oxygen atom. This will facilitate the release of H ⁺ by making O - H bond more polar and thus - Cl increases the acidity of acetic acid when attached at, position because of -I effect.

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