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KCET2013ChemistryChemical Equilibrium

The yield of the products in the reaction, A₂(g)+2 B(g) C(g)+Q kJ would be higher at

Options

  1. Ahigh temperature and high pressure
  2. Bhigh temperature and low pressure
  3. Clow temperature and high pressure
  4. Dlow temperature and low pressure

Correct answer

C. low temperature and high pressure

Step-by-step solution

A₂(g)+2 B(g) C(g)+Q k J Obviously, the forward reaction is exothermic. Thus, according to Le-Chatelier's principle, the lower is temperature, greater would be the yield of ammonia. Also, the forward reaction occurs with decrease in number of gaseous molecules. Thus, according to Le-Chatelier's principle an increase in pressure, will shift the equilibrium in a direction in which the number of gaseous molecules decreases. In other words high pressure will favour the formation of products.

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