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KCET2021ChemistryGeneral Organic Chemistry

Arrange benzene, n -hexane and ethyne in decreasing order of their acidic behaviour.

Options

  1. ABenzene >n -hexane > Ethyne
  2. Bn -hexane > Benzene > Ethyne
  3. CEthyne >n -hexane > Benzene
  4. DEthyne > Benzene >n -hexane

Correct answer

D. Ethyne > Benzene >n -hexane

Step-by-step solution

The decreasing order of acidic behaviour is ethyne > benzene >n -hexane Because carbon in ethyne, benzene and n -hexane are s p, s p² and s p³ hybridised respectively. The carbocation formed after the removal of ' H ' is more stable in s p hybridised carbon atom because of high electronegativity due to more s -character.

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