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KCET2013ChemistrySolid State

Which of the following is diamagnetic?

Options

  1. AH ₂⁺
  2. BHe ₂⁺
  3. CO ₂
  4. DN ₂

Correct answer

D. N ₂

Step-by-step solution

MO configuration of H ₂⁺: 1 s¹ MO configuration of He ₂⁺: 1 s², ^ * s¹ MO configuration of N ₂ : 1 s² , ซั 1 s², 2 s², * 2 s², 2 p_ y ²= 2 p_ z ², 2 p_ x ² MO configuration of O ₂ : 1 s², ^ * 1 s², 2 s², ^ * 2 s², 2 p_ x ², 2 p_ y ²= 2 p_ z ², 2 p_ y ¹= _ ^ * 2 p_ z ¹ Hence, O ₂ is paramagnetic as it possesses two unpaired electrons.

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